Phosphorus status of Eutric Cambisols polluted by P‐containing immissions: Results of 31P NMR spectroscopy and chemical analysis

Research output: Contribution to journalArticleResearchpeer review

Authors

External Research Organisations

  • Lomonosov Moscow State University
  • University of Bayreuth
View graph of relations

Details

Original languageEnglish
Pages (from-to)293-298
Number of pages6
JournalZeitschrift für Pflanzenernährung und Bodenkunde
Volume158
Issue number3
Publication statusPublished - 1995
Externally publishedYes

Abstract

The P status of an unpolluted Cambisol was compared with that of a polluted Cambisol receiving high P deposition that arise from a fertilizer factory near Novgorod, NW Russia. Experiments included P fractionation, P adsorption experiments and 31P NMR spectroscopy. In the O, A and AB horizons of the unpolluted soil organic P was the dominating fraction. Anthropogenic P accumulation was restricted to the O, A and AB horizons and amounted 692 kg ha−1, representing the sum of P deposition within 20 years of factory operation. Most of the additional P was extractable inorganic P. Hence, P extractability increased from 54‐75 % in the unpolluted soil to 66‐83 % in the polluted soil. Ca‐phosphates were mainly accumulated in the forest floor, while Al‐ and Fe‐phosphates were concentrated in the A and AB horizons. Organic P showed only a slight increase due to P deposition. This increase was only due to accumulation of stable monoester‐P, while the stock of the more labile diester‐P and phosphonates in the polluted soil was only half of that in the unpolluted soil.

ASJC Scopus subject areas

Sustainable Development Goals

Cite this

Phosphorus status of Eutric Cambisols polluted by P‐containing immissions: Results of 31P NMR spectroscopy and chemical analysis. / Makarov, Mikhail I.; Guggenberger, Georg; Alt, Helmut G. et al.
In: Zeitschrift für Pflanzenernährung und Bodenkunde, Vol. 158, No. 3, 1995, p. 293-298.

Research output: Contribution to journalArticleResearchpeer review

Download
@article{3eb83b6485574ed7a3c30c41ef1ebf1f,
title = "Phosphorus status of Eutric Cambisols polluted by P‐containing immissions:: Results of 31P NMR spectroscopy and chemical analysis",
abstract = "The P status of an unpolluted Cambisol was compared with that of a polluted Cambisol receiving high P deposition that arise from a fertilizer factory near Novgorod, NW Russia. Experiments included P fractionation, P adsorption experiments and 31P NMR spectroscopy. In the O, A and AB horizons of the unpolluted soil organic P was the dominating fraction. Anthropogenic P accumulation was restricted to the O, A and AB horizons and amounted 692 kg ha−1, representing the sum of P deposition within 20 years of factory operation. Most of the additional P was extractable inorganic P. Hence, P extractability increased from 54‐75 % in the unpolluted soil to 66‐83 % in the polluted soil. Ca‐phosphates were mainly accumulated in the forest floor, while Al‐ and Fe‐phosphates were concentrated in the A and AB horizons. Organic P showed only a slight increase due to P deposition. This increase was only due to accumulation of stable monoester‐P, while the stock of the more labile diester‐P and phosphonates in the polluted soil was only half of that in the unpolluted soil.",
author = "Makarov, {Mikhail I.} and Georg Guggenberger and Alt, {Helmut G.} and Wolfgang Zech",
year = "1995",
doi = "10.1002/jpln.19951580313",
language = "English",
volume = "158",
pages = "293--298",
journal = "Zeitschrift f{\"u}r Pflanzenern{\"a}hrung und Bodenkunde",
issn = "0044-3263",
publisher = "Wiley-VCH Verlag",
number = "3",

}

Download

TY - JOUR

T1 - Phosphorus status of Eutric Cambisols polluted by P‐containing immissions:

T2 - Results of 31P NMR spectroscopy and chemical analysis

AU - Makarov, Mikhail I.

AU - Guggenberger, Georg

AU - Alt, Helmut G.

AU - Zech, Wolfgang

PY - 1995

Y1 - 1995

N2 - The P status of an unpolluted Cambisol was compared with that of a polluted Cambisol receiving high P deposition that arise from a fertilizer factory near Novgorod, NW Russia. Experiments included P fractionation, P adsorption experiments and 31P NMR spectroscopy. In the O, A and AB horizons of the unpolluted soil organic P was the dominating fraction. Anthropogenic P accumulation was restricted to the O, A and AB horizons and amounted 692 kg ha−1, representing the sum of P deposition within 20 years of factory operation. Most of the additional P was extractable inorganic P. Hence, P extractability increased from 54‐75 % in the unpolluted soil to 66‐83 % in the polluted soil. Ca‐phosphates were mainly accumulated in the forest floor, while Al‐ and Fe‐phosphates were concentrated in the A and AB horizons. Organic P showed only a slight increase due to P deposition. This increase was only due to accumulation of stable monoester‐P, while the stock of the more labile diester‐P and phosphonates in the polluted soil was only half of that in the unpolluted soil.

AB - The P status of an unpolluted Cambisol was compared with that of a polluted Cambisol receiving high P deposition that arise from a fertilizer factory near Novgorod, NW Russia. Experiments included P fractionation, P adsorption experiments and 31P NMR spectroscopy. In the O, A and AB horizons of the unpolluted soil organic P was the dominating fraction. Anthropogenic P accumulation was restricted to the O, A and AB horizons and amounted 692 kg ha−1, representing the sum of P deposition within 20 years of factory operation. Most of the additional P was extractable inorganic P. Hence, P extractability increased from 54‐75 % in the unpolluted soil to 66‐83 % in the polluted soil. Ca‐phosphates were mainly accumulated in the forest floor, while Al‐ and Fe‐phosphates were concentrated in the A and AB horizons. Organic P showed only a slight increase due to P deposition. This increase was only due to accumulation of stable monoester‐P, while the stock of the more labile diester‐P and phosphonates in the polluted soil was only half of that in the unpolluted soil.

UR - http://www.scopus.com/inward/record.url?scp=0000377487&partnerID=8YFLogxK

U2 - 10.1002/jpln.19951580313

DO - 10.1002/jpln.19951580313

M3 - Article

AN - SCOPUS:0000377487

VL - 158

SP - 293

EP - 298

JO - Zeitschrift für Pflanzenernährung und Bodenkunde

JF - Zeitschrift für Pflanzenernährung und Bodenkunde

SN - 0044-3263

IS - 3

ER -

By the same author(s)