Phonon spectra of 2:1 mullite in infrared and Raman experiments

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  • C. H. Rüscher

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Original languageEnglish
Pages (from-to)50-55
Number of pages6
JournalPhysics and chemistry of minerals
Volume23
Issue number1
Publication statusPublished - Feb 1996

Abstract

Single crystal Raman and infrared phonon spectra of mullite were measured. The number of modes, their frequencies and line profiles are analysed. The local structural changes associated with the formation of oxygen vacancies contribute to the appearence of modes in both the Raman and infrared spectra of mullite. The number of modes is increased compared with the degrees of freedom predicted by group theory for the mullite structure without oxygen vacancies.

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Phonon spectra of 2:1 mullite in infrared and Raman experiments. / Rüscher, C. H.
In: Physics and chemistry of minerals, Vol. 23, No. 1, 02.1996, p. 50-55.

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