Details
Original language | English |
---|---|
Pages (from-to) | 1273-1277 |
Number of pages | 5 |
Journal | SOLID STATE IONICS |
Volume | 101-103 |
Issue number | PART 1 |
Publication status | Published - Nov 1997 |
Externally published | Yes |
Abstract
This study deals with host-guest interactions in clathrasils. Silica sodalites with enclosed ethyleneglycol (EG), ethanolamine (EA) and ethylenediamine (ED), respectively, were chosen as a basic model system. The inclusion of the stereochemically similar molecules EG, EA and ED in an identical environment leads to drastic changes in the properties of the different silica sodalites. The thermal properties are investigated by differential scanning calorimetry and temperature-dependent powder X-ray diffractometry.
Keywords
- Host-guest interactions, Phase transitions, Thermal properties
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
- Materials Science(all)
- General Materials Science
- Physics and Astronomy(all)
- Condensed Matter Physics
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In: SOLID STATE IONICS, Vol. 101-103, No. PART 1, 11.1997, p. 1273-1277.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Phase transitions and thermal behaviour of silica sodalites
AU - Braunbarth, Carola M.
AU - Behrens, Peter
AU - Felsche, Jürgen
AU - Van De Goor, G.
N1 - Funding information: We thank Prof. Dr. J. Ihringer from the Institut fur Kristallographie (University of Tubingen) for the measurements of the temperature-variable X-ray diffractogramsa nd the Deutsche Forschungsgemein-schaft (DFG) for financial support.
PY - 1997/11
Y1 - 1997/11
N2 - This study deals with host-guest interactions in clathrasils. Silica sodalites with enclosed ethyleneglycol (EG), ethanolamine (EA) and ethylenediamine (ED), respectively, were chosen as a basic model system. The inclusion of the stereochemically similar molecules EG, EA and ED in an identical environment leads to drastic changes in the properties of the different silica sodalites. The thermal properties are investigated by differential scanning calorimetry and temperature-dependent powder X-ray diffractometry.
AB - This study deals with host-guest interactions in clathrasils. Silica sodalites with enclosed ethyleneglycol (EG), ethanolamine (EA) and ethylenediamine (ED), respectively, were chosen as a basic model system. The inclusion of the stereochemically similar molecules EG, EA and ED in an identical environment leads to drastic changes in the properties of the different silica sodalites. The thermal properties are investigated by differential scanning calorimetry and temperature-dependent powder X-ray diffractometry.
KW - Host-guest interactions
KW - Phase transitions
KW - Thermal properties
UR - http://www.scopus.com/inward/record.url?scp=0031272544&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0031272544
VL - 101-103
SP - 1273
EP - 1277
JO - SOLID STATE IONICS
JF - SOLID STATE IONICS
SN - 0167-2738
IS - PART 1
ER -