Pattern-forming nanoprecipitates in NiTi-related high entropy shape memory alloys

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Original languageEnglish
Pages (from-to)132-135
Number of pages4
JournalScripta materialia
Volume186
Publication statusPublished - 28 May 2020

Abstract

The microstructure and the fracture behavior of TiZrHfCoNiCu high entropy shape memory alloys with two different compositions were investigated. An unusual microstructure featuring pattern-forming nanoprecipitates was observed in dendritic and the interdendritic regions of both alloys. The unique higher-level order of these precipitates does not follow concentration gradients but is influenced by homogeneity and mechanical stress. The results also demonstrate that high entropy alloys are not necessarily homogeneous single-phase solid solutions. Moreover, it appears that solid solution strengthening as the primary mechanism also has to be questioned.

Keywords

    Electron backscattering patterns (EBSP), High entropy alloys (HEA), Interfacial segregation, Nanocrystalline microstructure, Shape memory alloys (SMA)

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Pattern-forming nanoprecipitates in NiTi-related high entropy shape memory alloys. / Hinte, Christian; Barienti, Khemais; Steinbrücker, Jan et al.
In: Scripta materialia, Vol. 186, 28.05.2020, p. 132-135.

Research output: Contribution to journalArticleResearchpeer review

Hinte C, Barienti K, Steinbrücker J, Gerstein G, Swider MA, Herbst S et al. Pattern-forming nanoprecipitates in NiTi-related high entropy shape memory alloys. Scripta materialia. 2020 May 28;186:132-135. doi: 10.1016/j.scriptamat.2020.05.007
Hinte, Christian ; Barienti, Khemais ; Steinbrücker, Jan et al. / Pattern-forming nanoprecipitates in NiTi-related high entropy shape memory alloys. In: Scripta materialia. 2020 ; Vol. 186. pp. 132-135.
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title = "Pattern-forming nanoprecipitates in NiTi-related high entropy shape memory alloys",
abstract = "The microstructure and the fracture behavior of TiZrHfCoNiCu high entropy shape memory alloys with two different compositions were investigated. An unusual microstructure featuring pattern-forming nanoprecipitates was observed in dendritic and the interdendritic regions of both alloys. The unique higher-level order of these precipitates does not follow concentration gradients but is influenced by homogeneity and mechanical stress. The results also demonstrate that high entropy alloys are not necessarily homogeneous single-phase solid solutions. Moreover, it appears that solid solution strengthening as the primary mechanism also has to be questioned.",
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author = "Christian Hinte and Khemais Barienti and Jan Steinbr{\"u}cker and Gregory Gerstein and Swider, {Mark Alan} and Sebastian Herbst and Gunther Eggeler and Maier, {Hans J{\"u}rgen}",
note = "Funding information: Financial support by Deutsche Forschungsgemeinschaft (German Research Foundation) under project nos. 388671975 and 313773923 is gratefully acknowledged. The authors also thank G. S. Firstov for discussions on the topic.",
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T1 - Pattern-forming nanoprecipitates in NiTi-related high entropy shape memory alloys

AU - Hinte, Christian

AU - Barienti, Khemais

AU - Steinbrücker, Jan

AU - Gerstein, Gregory

AU - Swider, Mark Alan

AU - Herbst, Sebastian

AU - Eggeler, Gunther

AU - Maier, Hans Jürgen

N1 - Funding information: Financial support by Deutsche Forschungsgemeinschaft (German Research Foundation) under project nos. 388671975 and 313773923 is gratefully acknowledged. The authors also thank G. S. Firstov for discussions on the topic.

PY - 2020/5/28

Y1 - 2020/5/28

N2 - The microstructure and the fracture behavior of TiZrHfCoNiCu high entropy shape memory alloys with two different compositions were investigated. An unusual microstructure featuring pattern-forming nanoprecipitates was observed in dendritic and the interdendritic regions of both alloys. The unique higher-level order of these precipitates does not follow concentration gradients but is influenced by homogeneity and mechanical stress. The results also demonstrate that high entropy alloys are not necessarily homogeneous single-phase solid solutions. Moreover, it appears that solid solution strengthening as the primary mechanism also has to be questioned.

AB - The microstructure and the fracture behavior of TiZrHfCoNiCu high entropy shape memory alloys with two different compositions were investigated. An unusual microstructure featuring pattern-forming nanoprecipitates was observed in dendritic and the interdendritic regions of both alloys. The unique higher-level order of these precipitates does not follow concentration gradients but is influenced by homogeneity and mechanical stress. The results also demonstrate that high entropy alloys are not necessarily homogeneous single-phase solid solutions. Moreover, it appears that solid solution strengthening as the primary mechanism also has to be questioned.

KW - Electron backscattering patterns (EBSP)

KW - High entropy alloys (HEA)

KW - Interfacial segregation

KW - Nanocrystalline microstructure

KW - Shape memory alloys (SMA)

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