TY - JOUR

T1 - Palynofacies, micropalaeontology, and source rock evaluation of non-marine Jurassic–Cretaceous boundary deposits from northern Germany - Implications for palaeoenvironment and hydrocarbon potential

AU - Schneider, Anton Christoph

AU - Mutterlose, Jörg

AU - Blumenberg, Martin

AU - Heimhofer, Ulrich

AU - Luppold, Friedrich W.

N1 - Funding information: We thank ExxonMobil Production Deutschland GmbH and the Landesamt für Bergbau, Energie und Geologie (LBEG, Hannover) for giving access to the core material. Lena Rippolz and Hauke Thöle are thanked for providing the slides of core Scharnhorst-3 (S-3). Further we thank Barbara Piesker and Gabriele Grützner for sample preparation and Petra Adam, Sylvia Kramer, and Georg Scheeder for analytical support (BGR).

PY - 2019/5

Y1 - 2019/5

N2 - The Jurassic–Cretaceous boundary interval of northern Germany is characterised by non-marine deposits attributed to the Purbeck and Wealden facies. These organic-rich sediments were deposited under restricted, brackish-lacustrine conditions in a palaeogeographically isolated basin (Lower Saxony Basin). Rock-Eval and δ 13 C org measurements were performed to characterise the composition and distribution of the organic matter, to determine the kerogen type chemically, and to define the quantity and maturity of the organic matter. A strong correlation between the optical characteristics, documented by the palynofacies analysis, and the chemical kerogen analyses have led to a better understanding of the palaeoenvironment and the processes which caused the organic matter enrichment. The samples studied from the basin center show a high petroleum generation potential, their estimated maturity is close to the onset of oil generation. Total organic carbon (TOC) concentrations of up to 18% have been measured, hydrogen index values reach up to 1185 mg HC/g TOC. The kerogen assemblages in two basinal successions are dominated by granular amorphous organic material (AOM), dinoflagellate cysts, and Botryococcus algae. In a more marginal succession continent-derived debris (phytoclasts, pollen and spores) is dominant. The AOM is interpreted to have originated either from phytoplankton (probably dinoflagellate cysts and Botryococcus), or its bacterial/archaeal degradation products formed under anoxic conditions. TOC-rich samples which are dominated by these amorphous kerogens show the highest petroleum potential, the AOM therefore plays a key role for the petroleum generation. The long-term climatic and hydrological evolution of the Lower Saxony Basin, which is based on palynomorphs, ostracods, and benthic foraminifera, is here interpreted by a five-stage model. Fluctuations in the salinity of the water bodies are directly reflected by the ratio between different freshwater and brackish-marine organisms as well dinoflagellate cyst diversity; five different cyst morphogroups are used for palaeoenvironmental interpretations. The deposition of TOC-rich beds in the German Wealden can be best explained by both high primary productivity and the establishment of prolonged phases of bottom water anoxia in a brackish-lacustrine depositional environment. Ecological conditions supporting enhanced productivity and preservation of the algal/bacterial-derived organic matter were most favourable during the mid–late Berriasian (Wealden 1–4).

AB - The Jurassic–Cretaceous boundary interval of northern Germany is characterised by non-marine deposits attributed to the Purbeck and Wealden facies. These organic-rich sediments were deposited under restricted, brackish-lacustrine conditions in a palaeogeographically isolated basin (Lower Saxony Basin). Rock-Eval and δ 13 C org measurements were performed to characterise the composition and distribution of the organic matter, to determine the kerogen type chemically, and to define the quantity and maturity of the organic matter. A strong correlation between the optical characteristics, documented by the palynofacies analysis, and the chemical kerogen analyses have led to a better understanding of the palaeoenvironment and the processes which caused the organic matter enrichment. The samples studied from the basin center show a high petroleum generation potential, their estimated maturity is close to the onset of oil generation. Total organic carbon (TOC) concentrations of up to 18% have been measured, hydrogen index values reach up to 1185 mg HC/g TOC. The kerogen assemblages in two basinal successions are dominated by granular amorphous organic material (AOM), dinoflagellate cysts, and Botryococcus algae. In a more marginal succession continent-derived debris (phytoclasts, pollen and spores) is dominant. The AOM is interpreted to have originated either from phytoplankton (probably dinoflagellate cysts and Botryococcus), or its bacterial/archaeal degradation products formed under anoxic conditions. TOC-rich samples which are dominated by these amorphous kerogens show the highest petroleum potential, the AOM therefore plays a key role for the petroleum generation. The long-term climatic and hydrological evolution of the Lower Saxony Basin, which is based on palynomorphs, ostracods, and benthic foraminifera, is here interpreted by a five-stage model. Fluctuations in the salinity of the water bodies are directly reflected by the ratio between different freshwater and brackish-marine organisms as well dinoflagellate cyst diversity; five different cyst morphogroups are used for palaeoenvironmental interpretations. The deposition of TOC-rich beds in the German Wealden can be best explained by both high primary productivity and the establishment of prolonged phases of bottom water anoxia in a brackish-lacustrine depositional environment. Ecological conditions supporting enhanced productivity and preservation of the algal/bacterial-derived organic matter were most favourable during the mid–late Berriasian (Wealden 1–4).

KW - Amorphous organic matter

KW - Berriasian

KW - Brackish-lacustrine

KW - Lower saxony basin

KW - Oil shales

KW - Petroleum potential

KW - Purbeck

KW - Wealden

UR - http://www.scopus.com/inward/record.url?scp=85063127338&partnerID=8YFLogxK

U2 - 10.1016/j.marpetgeo.2019.02.016

DO - 10.1016/j.marpetgeo.2019.02.016

M3 - Article

AN - SCOPUS:85063127338

VL - 103

SP - 526

EP - 548

JO - Marine and Petroleum Geology

JF - Marine and Petroleum Geology

SN - 0264-8172

ER -