Details
| Original language | English |
|---|---|
| Pages (from-to) | 717-730 |
| Number of pages | 14 |
| Journal | Advanced Synthesis and Catalysis |
| Volume | 350 |
| Issue number | 5 |
| Publication status | Published - 18 Mar 2008 |
Abstract
Palladium particles were generated by reduction of palladate anions bound to an ion exchange resin inside microreactors. The size and distribution of the palladium particles differed substantially depending on the degree of cross-linking and the density of ion exchange sites on the polymer/glass composites, the latter parameter having a larger influence than the former. The polymer phase of the composite materials was used for the loading with clusters composed of palladium particles which are 1 to 10 nm in diameter. The reactivity and stability of six different palladium-doped polymer/glass composite samples for transfer hydrogenations was investigated both under conventional and microwave heating in the batch mode as well as under continuous flow conditions using the cyclohexene-promoted transfer hydrogenation of ethyl cinnamate as a model reaction. Regarding the heating method it was found that catalysts that are composed of larger metal particles perform better under microwave irradiating conditions whereas samples with smaller particle sizes perform better under conventional heating. Comparing batch experiments with flow-through experiments the latter technique gives better conversion. Reusability was better in microwave heated experiments than in traditional heating.
Keywords
- Enabling technologies, Hydrogenation, Immobilization, Microreactors, Microwave heating, Palladium
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- Organic Chemistry
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In: Advanced Synthesis and Catalysis, Vol. 350, No. 5, 18.03.2008, p. 717-730.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Palladium(0) nanoparticles on glass-polymer composite materials as recyclable catalysts
T2 - A comparison study on their use in batch and continuous flow processes
AU - Mennecke, Klaas
AU - Cecilia, Raul
AU - Glasnov, Toma N.
AU - Gruhl, Susanne
AU - Vogt, Carla
AU - Feldhoff, Armin
AU - Vargas, M. A.Larrubia
AU - Kappe, C. Oliver
AU - Kunz, Ulrich
AU - Kirschning, Andreas
PY - 2008/3/18
Y1 - 2008/3/18
N2 - Palladium particles were generated by reduction of palladate anions bound to an ion exchange resin inside microreactors. The size and distribution of the palladium particles differed substantially depending on the degree of cross-linking and the density of ion exchange sites on the polymer/glass composites, the latter parameter having a larger influence than the former. The polymer phase of the composite materials was used for the loading with clusters composed of palladium particles which are 1 to 10 nm in diameter. The reactivity and stability of six different palladium-doped polymer/glass composite samples for transfer hydrogenations was investigated both under conventional and microwave heating in the batch mode as well as under continuous flow conditions using the cyclohexene-promoted transfer hydrogenation of ethyl cinnamate as a model reaction. Regarding the heating method it was found that catalysts that are composed of larger metal particles perform better under microwave irradiating conditions whereas samples with smaller particle sizes perform better under conventional heating. Comparing batch experiments with flow-through experiments the latter technique gives better conversion. Reusability was better in microwave heated experiments than in traditional heating.
AB - Palladium particles were generated by reduction of palladate anions bound to an ion exchange resin inside microreactors. The size and distribution of the palladium particles differed substantially depending on the degree of cross-linking and the density of ion exchange sites on the polymer/glass composites, the latter parameter having a larger influence than the former. The polymer phase of the composite materials was used for the loading with clusters composed of palladium particles which are 1 to 10 nm in diameter. The reactivity and stability of six different palladium-doped polymer/glass composite samples for transfer hydrogenations was investigated both under conventional and microwave heating in the batch mode as well as under continuous flow conditions using the cyclohexene-promoted transfer hydrogenation of ethyl cinnamate as a model reaction. Regarding the heating method it was found that catalysts that are composed of larger metal particles perform better under microwave irradiating conditions whereas samples with smaller particle sizes perform better under conventional heating. Comparing batch experiments with flow-through experiments the latter technique gives better conversion. Reusability was better in microwave heated experiments than in traditional heating.
KW - Enabling technologies
KW - Hydrogenation
KW - Immobilization
KW - Microreactors
KW - Microwave heating
KW - Palladium
UR - http://www.scopus.com/inward/record.url?scp=41949099721&partnerID=8YFLogxK
U2 - 10.1002/adsc.200700510
DO - 10.1002/adsc.200700510
M3 - Article
AN - SCOPUS:41949099721
VL - 350
SP - 717
EP - 730
JO - Advanced Synthesis and Catalysis
JF - Advanced Synthesis and Catalysis
SN - 1615-4150
IS - 5
ER -