Details
| Translated title of the contribution | Oxazaborolidine als Katalysatoren für enantioselektive Cycloadditionen: Jetzt auch [2+2]! |
|---|---|
| Original language | English |
| Pages (from-to) | 3492-3495 |
| Number of pages | 4 |
| Journal | Angewandte Chemie |
| Volume | 47 |
| Issue number | 19 |
| Publication status | Published - 21 Apr 2008 |
Abstract
(Chemical Equation Presented) More and more applicable: The adduct of an oxazaborolidine and aluminum tribromide (see picture) turns out to be an efficient catalyst not only for enantioselective Diels-Alder reactions but now also for enantioselective [2+2] cycloadditions. The products are important enantiomerically pure building blocks for the synthesis of complex organic compounds.
Keywords
- Asymmetric catalysis, Cycloadditions, Cyclobutane, Lewis acids, Oxazaborolidine
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- General Chemistry
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In: Angewandte Chemie , Vol. 47, No. 19, 21.04.2008, p. 3492-3495.
Research output: Contribution to journal › Review article › Research › peer review
}
TY - JOUR
T1 - Oxazaborolidines as catalysts for enantioselective cycloadditions
T2 - Now [2+2]!
AU - Butenschön, Holger
PY - 2008/4/21
Y1 - 2008/4/21
N2 - (Chemical Equation Presented) More and more applicable: The adduct of an oxazaborolidine and aluminum tribromide (see picture) turns out to be an efficient catalyst not only for enantioselective Diels-Alder reactions but now also for enantioselective [2+2] cycloadditions. The products are important enantiomerically pure building blocks for the synthesis of complex organic compounds.
AB - (Chemical Equation Presented) More and more applicable: The adduct of an oxazaborolidine and aluminum tribromide (see picture) turns out to be an efficient catalyst not only for enantioselective Diels-Alder reactions but now also for enantioselective [2+2] cycloadditions. The products are important enantiomerically pure building blocks for the synthesis of complex organic compounds.
KW - Asymmetric catalysis
KW - Cycloadditions
KW - Cyclobutane
KW - Lewis acids
KW - Oxazaborolidine
UR - http://www.scopus.com/inward/record.url?scp=53549112783&partnerID=8YFLogxK
U2 - 10.1002/anie.200800574
DO - 10.1002/anie.200800574
M3 - Review article
AN - SCOPUS:53549112783
VL - 47
SP - 3492
EP - 3495
JO - Angewandte Chemie
JF - Angewandte Chemie
SN - 1433-7851
IS - 19
ER -