Details
| Original language | English |
|---|---|
| Article number | ss-2016-z0440-op |
| Pages (from-to) | 145-150 |
| Number of pages | 6 |
| Journal | Synthesis (Germany) |
| Volume | 49 |
| Issue number | 1 |
| Publication status | Published - 3 Jan 2017 |
Abstract
A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.
Keywords
- flow chemistry, organocatalysis, phenols, phosphine, polymer-supported catalyst, rearrangement
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- Organic Chemistry
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In: Synthesis (Germany), Vol. 49, No. 1, ss-2016-z0440-op, 03.01.2017, p. 145-150.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Organocatalytic Alkyne Isomerizations under Flow Conditions Using Heterogeneous Bifunctional Polystyrene Bearing Phosphine and Phenol Groups
AU - Ceylan, Sascha
AU - Law, Henry Chun Hin
AU - Kirschning, Andreas
AU - Toy, Patrick H.
N1 - Funding information: This research was funded in part by the Research Grants Council of the Hong Kong S. A. R., P. R. of China (Project No. HKU 704108P and GHK 031/07), and the Deutscher Akademischer Austauschdienst (DAAD).
PY - 2017/1/3
Y1 - 2017/1/3
N2 - A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.
AB - A heterogeneous bifunctional polymer bearing phosphine and phenol groups was developed to catalyze the isomerization of electronically activated alkynes. This organocatalytic process provided the corresponding (E,E)-dienes and was shown to work under both batch and flow conditions.
KW - flow chemistry
KW - organocatalysis
KW - phenols
KW - phosphine
KW - polymer-supported catalyst
KW - rearrangement
UR - http://www.scopus.com/inward/record.url?scp=84991202469&partnerID=8YFLogxK
U2 - 10.1055/s-0036-1588589
DO - 10.1055/s-0036-1588589
M3 - Article
AN - SCOPUS:84991202469
VL - 49
SP - 145
EP - 150
JO - Synthesis (Germany)
JF - Synthesis (Germany)
SN - 0039-7881
IS - 1
M1 - ss-2016-z0440-op
ER -