Details
| Original language | English |
|---|---|
| Pages (from-to) | 17851-17855 |
| Number of pages | 5 |
| Journal | Physical Chemistry Chemical Physics |
| Volume | 18 |
| Issue number | 27 |
| Publication status | Published - 17 Mar 2016 |
Abstract
The rotational spectra of two isotopologues (CF335Cl-CO and CF337Cl-CO) of the CF3Cl-CO adduct have been investigated and analyzed using supersonic-jet Fourier transform microwave spectroscopy, and found to have the features of a symmetric top. Rotational, centrifugal distortion, and nuclear quadrupole (35Cl and 37Cl) coupling constants have been precisely obtained from high-resolution measurements. The two subunits of the complex are held together via a Cl⋯C halogen bond interaction. Information on the internal dynamics and the dissociation energy of the complex is provided.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- General Physics and Astronomy
- Chemistry(all)
- Physical and Theoretical Chemistry
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In: Physical Chemistry Chemical Physics, Vol. 18, No. 27, 17.03.2016, p. 17851-17855.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - On the Cl⋯C halogen bond
T2 - A rotational study of CF3Cl-CO
AU - Caminati, Walther
AU - Evangelisti, Luca
AU - Feng, Gang
AU - Giuliano, Barbara M.
AU - Gou, Qian
AU - Melandri, Sonia
AU - Grabow, Jens Uwe
PY - 2016/3/17
Y1 - 2016/3/17
N2 - The rotational spectra of two isotopologues (CF335Cl-CO and CF337Cl-CO) of the CF3Cl-CO adduct have been investigated and analyzed using supersonic-jet Fourier transform microwave spectroscopy, and found to have the features of a symmetric top. Rotational, centrifugal distortion, and nuclear quadrupole (35Cl and 37Cl) coupling constants have been precisely obtained from high-resolution measurements. The two subunits of the complex are held together via a Cl⋯C halogen bond interaction. Information on the internal dynamics and the dissociation energy of the complex is provided.
AB - The rotational spectra of two isotopologues (CF335Cl-CO and CF337Cl-CO) of the CF3Cl-CO adduct have been investigated and analyzed using supersonic-jet Fourier transform microwave spectroscopy, and found to have the features of a symmetric top. Rotational, centrifugal distortion, and nuclear quadrupole (35Cl and 37Cl) coupling constants have been precisely obtained from high-resolution measurements. The two subunits of the complex are held together via a Cl⋯C halogen bond interaction. Information on the internal dynamics and the dissociation energy of the complex is provided.
UR - http://www.scopus.com/inward/record.url?scp=84979021219&partnerID=8YFLogxK
U2 - 10.1039/c6cp01059h
DO - 10.1039/c6cp01059h
M3 - Article
AN - SCOPUS:84979021219
VL - 18
SP - 17851
EP - 17855
JO - Physical Chemistry Chemical Physics
JF - Physical Chemistry Chemical Physics
SN - 1463-9076
IS - 27
ER -