Novel Tricarbonyl(η4‐dihydroacepentalene)iron Complexes and Tricarbonyl(η2‐dihydroacepentalene)ferrates(−2)

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Translated title of the contributionNeuartige Tricarbonyl(η4-dihydroacepentalen)eisen-Komplexe und Tricarbonyl-(η2-dihydroacepentalen)ferrate( — 2)
Original languageEnglish
Pages (from-to)707-708
Number of pages2
JournalAngewandte Chemie International Edition in English
Volume23
Issue number9
Publication statusPublished - Sept 1984
Externally publishedYes

Abstract

The first spectroscopically characterized (η2‐olefin)ferrates( – 2), 3, are formed on reduction of the novel (η4‐diene)iron complexes 2 with sodium. This reaction proceeds via a radical anion; high spin density at the iron is detected by ESR spectroscopy in the case of the reduction product of 2, NR2 = piperidino. (Figure Presented.)

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Novel Tricarbonyl(η4‐dihydroacepentalene)iron Complexes and Tricarbonyl(η2‐dihydroacepentalene)ferrates(−2). / Butenschön, Holger; de Meijere, Armin.
In: Angewandte Chemie International Edition in English, Vol. 23, No. 9, 09.1984, p. 707-708.

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abstract = "The first spectroscopically characterized (η2‐olefin)ferrates( – 2), 3, are formed on reduction of the novel (η4‐diene)iron complexes 2 with sodium. This reaction proceeds via a radical anion; high spin density at the iron is detected by ESR spectroscopy in the case of the reduction product of 2, NR2 = piperidino. (Figure Presented.)",
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