Nitrogen and boron doped carbon layer coated multiwall carbon nanotubes as high performance anode materials for lithium ion batteries

Research output: Contribution to journalArticleResearchpeer review

Authors

  • Bo Liu
  • Xiaolei Sun
  • Zhongquan Liao
  • Xueyi Lu
  • Lin Zhang
  • Guang-Ping Hao

Research Organisations

External Research Organisations

  • Technische Universität Dresden
  • Nankai University
  • Fraunhofer Institute for Ceramic Technologies and Systems (IKTS)
  • Dalian University of Technology
  • Leibniz Institute for Solid State and Materials Research Dresden (IFW)
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Details

Original languageEnglish
Article number5633
JournalScientific reports
Volume11
Publication statusPublished - 11 Mar 2021

Abstract

Lithium ion batteries (LIBs) are at present widely used as energy storage and conversion device in our daily life. However, due to the limited power density, the application of LIBs is still restricted in some areas such as commercial vehicles or heavy-duty trucks. An effective strategy to solve this problem is to increase energy density through the development of battery materials. At the same time, a stable long cycling battery is a great demand of environmental protection and industry. Herein we present our new materials, nitrogen and boron doped carbon layer coated multiwall carbon nanotubes (NBC@MWCNTs), which can be used as anodes for LIBs. The electrochemical results demonstrate that the designed NBC@MWCNTs electrode possesses high stable capacity over an ultra-long cycling lifespan (5000 cycles) and superior rate capability even at very high current density (67.5 A g<jats:sup/>−1). Such impressive lithium storage properties could be ascribed to the synergistic coupling effect of the distinctive structural features, the reduced diffusion length of lithium ions, more active sites generated by doped atoms for lithium storage, as well as the enhancement of the electrode structural integrity. Taken together, these results indicate that the N, B-doped carbon@MWCNTs materials may have great potential for applications in next-generation high performance rechargeable batteries.

ASJC Scopus subject areas

Sustainable Development Goals

Cite this

Nitrogen and boron doped carbon layer coated multiwall carbon nanotubes as high performance anode materials for lithium ion batteries. / Liu, Bo; Sun, Xiaolei ; Liao, Zhongquan et al.
In: Scientific reports, Vol. 11, 5633, 11.03.2021.

Research output: Contribution to journalArticleResearchpeer review

Download
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abstract = "Lithium ion batteries (LIBs) are at present widely used as energy storage and conversion device in our daily life. However, due to the limited power density, the application of LIBs is still restricted in some areas such as commercial vehicles or heavy-duty trucks. An effective strategy to solve this problem is to increase energy density through the development of battery materials. At the same time, a stable long cycling battery is a great demand of environmental protection and industry. Herein we present our new materials, nitrogen and boron doped carbon layer coated multiwall carbon nanotubes (NBC@MWCNTs), which can be used as anodes for LIBs. The electrochemical results demonstrate that the designed NBC@MWCNTs electrode possesses high stable capacity over an ultra-long cycling lifespan (5000 cycles) and superior rate capability even at very high current density (67.5 A g−1). Such impressive lithium storage properties could be ascribed to the synergistic coupling effect of the distinctive structural features, the reduced diffusion length of lithium ions, more active sites generated by doped atoms for lithium storage, as well as the enhancement of the electrode structural integrity. Taken together, these results indicate that the N, B-doped carbon@MWCNTs materials may have great potential for applications in next-generation high performance rechargeable batteries.",
author = "Bo Liu and Xiaolei Sun and Zhongquan Liao and Xueyi Lu and Lin Zhang and Guang-Ping Hao",
note = "Funding Information: X.S. acknowledges the financial supports from the National Natural Science Foundation of China (Grant No. 11904179), the Fundamental Research Funds for the Central Universities, Nankai University (Grant No. 63201069). All authors are grateful for the Open Access Funding provided by Projekt DEAL. ",
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AU - Liu, Bo

AU - Sun, Xiaolei

AU - Liao, Zhongquan

AU - Lu, Xueyi

AU - Zhang, Lin

AU - Hao, Guang-Ping

N1 - Funding Information: X.S. acknowledges the financial supports from the National Natural Science Foundation of China (Grant No. 11904179), the Fundamental Research Funds for the Central Universities, Nankai University (Grant No. 63201069). All authors are grateful for the Open Access Funding provided by Projekt DEAL.

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