Details
Original language | English |
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Pages (from-to) | 1177-1179 |
Number of pages | 3 |
Journal | Australian journal of chemistry |
Volume | 64 |
Issue number | 8 |
Publication status | Published - 19 Aug 2011 |
Abstract
Thin films of 1,3-diethylbenzimidazol-2-ylidene (BIEt) were fabricated from THF solution on solid gold substrates and characterised by high-resolution X-ray photoelectron and near-edge X-ray absorption fine structure spectroscopy. The surface-analytical data are in accord with the formation of self-assembled monolayers of BIEt molecules exhibiting an approximately vertical orientation on the substrate. The crystal structure of (BIEt)2 was also determined.
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In: Australian journal of chemistry, Vol. 64, No. 8, 19.08.2011, p. 1177-1179.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - NHC-based self-assembled monolayers on solid gold substrates
AU - Weidner, Tobias
AU - Baio, Joe E.
AU - Mundstock, Alexander
AU - Große, Christoph
AU - Karthäuser, Silvia
AU - Bruhn, Clemens
AU - Siemeling, Ulrich
N1 - Funding Information: This work was funded in part by NESAC-BIO (NIH grant EB-002027). T. W. thanks the Deutsche Forschungsgemeinschaft for a research fellowship. T. W. and J. E. B. thank David G. Castner for support and Daniel Fischer and Cherno Jaye (NIST) for providing them with the experimental equipment for NEXAFS spectroscopy and their help at the synchrotron. NEXAFS studies were performed at the NSLS, Brookhaven National Laboratory, which is supported by the USA Department of Energy, Division of Materials Science and Division of Chemical Sciences.
PY - 2011/8/19
Y1 - 2011/8/19
N2 - Thin films of 1,3-diethylbenzimidazol-2-ylidene (BIEt) were fabricated from THF solution on solid gold substrates and characterised by high-resolution X-ray photoelectron and near-edge X-ray absorption fine structure spectroscopy. The surface-analytical data are in accord with the formation of self-assembled monolayers of BIEt molecules exhibiting an approximately vertical orientation on the substrate. The crystal structure of (BIEt)2 was also determined.
AB - Thin films of 1,3-diethylbenzimidazol-2-ylidene (BIEt) were fabricated from THF solution on solid gold substrates and characterised by high-resolution X-ray photoelectron and near-edge X-ray absorption fine structure spectroscopy. The surface-analytical data are in accord with the formation of self-assembled monolayers of BIEt molecules exhibiting an approximately vertical orientation on the substrate. The crystal structure of (BIEt)2 was also determined.
UR - http://www.scopus.com/inward/record.url?scp=80051960495&partnerID=8YFLogxK
U2 - 10.1071/CH11173
DO - 10.1071/CH11173
M3 - Article
AN - SCOPUS:80051960495
VL - 64
SP - 1177
EP - 1179
JO - Australian journal of chemistry
JF - Australian journal of chemistry
SN - 0004-9425
IS - 8
ER -