Details
| Original language | English |
|---|---|
| Title of host publication | Ist Syn TOP Smart Synthesis and Technologies for Organic Processes |
| Pages | 37-40 |
| Number of pages | 4 |
| Edition | 2039 |
| Publication status | Published - 2008 |
Publication series
| Name | VDI Berichte |
|---|---|
| Number | 2039 |
| ISSN (Print) | 0083-5560 |
Abstract
Based on polymer/glass composite materials developed for catalytic distillation purposes we improved these materials for flow-through applications in organic synthesis [1]. During the last years we developed micro- and mini-reactors with a monolithic structure consisting of a glass carrier material with irregular shaped channels combined with a monolithic polymer phase [2,3]. This concept was used to attach functional groups or active sites on the polymer. With these reactors resin supported synthesis with anchored reactants as well as catalytic reactions were investigated. Meanwhile we enlarged the applicability of our composite reactors, including attachment of catalysts by ionic bonding and heating with microwaves [4,5]. Our presentation is an overview with respect to engineering aspects of the reactor design and operation and the versatile application in organic synthesis. Preparation of the reactors by polymerization with different monomers, attachment of functional groups, design of reactors for different purposes, flow-through operation performance, kinetic investigations and mass transfer experiments are given.
ASJC Scopus subject areas
- Engineering(all)
- General Engineering
Cite this
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Ist Syn TOP Smart Synthesis and Technologies for Organic Processes. 2039. ed. 2008. p. 37-40 (VDI Berichte; No. 2039).
Research output: Chapter in book/report/conference proceeding › Contribution to book/anthology › Research › peer review
}
TY - CHAP
T1 - Monolithic composite micro - Reactors
T2 - An enabling technology for improved organic synthesis
AU - Kunz, Ulrich
AU - Kirschning, Andreas
PY - 2008
Y1 - 2008
N2 - Based on polymer/glass composite materials developed for catalytic distillation purposes we improved these materials for flow-through applications in organic synthesis [1]. During the last years we developed micro- and mini-reactors with a monolithic structure consisting of a glass carrier material with irregular shaped channels combined with a monolithic polymer phase [2,3]. This concept was used to attach functional groups or active sites on the polymer. With these reactors resin supported synthesis with anchored reactants as well as catalytic reactions were investigated. Meanwhile we enlarged the applicability of our composite reactors, including attachment of catalysts by ionic bonding and heating with microwaves [4,5]. Our presentation is an overview with respect to engineering aspects of the reactor design and operation and the versatile application in organic synthesis. Preparation of the reactors by polymerization with different monomers, attachment of functional groups, design of reactors for different purposes, flow-through operation performance, kinetic investigations and mass transfer experiments are given.
AB - Based on polymer/glass composite materials developed for catalytic distillation purposes we improved these materials for flow-through applications in organic synthesis [1]. During the last years we developed micro- and mini-reactors with a monolithic structure consisting of a glass carrier material with irregular shaped channels combined with a monolithic polymer phase [2,3]. This concept was used to attach functional groups or active sites on the polymer. With these reactors resin supported synthesis with anchored reactants as well as catalytic reactions were investigated. Meanwhile we enlarged the applicability of our composite reactors, including attachment of catalysts by ionic bonding and heating with microwaves [4,5]. Our presentation is an overview with respect to engineering aspects of the reactor design and operation and the versatile application in organic synthesis. Preparation of the reactors by polymerization with different monomers, attachment of functional groups, design of reactors for different purposes, flow-through operation performance, kinetic investigations and mass transfer experiments are given.
UR - http://www.scopus.com/inward/record.url?scp=47349090015&partnerID=8YFLogxK
M3 - Contribution to book/anthology
AN - SCOPUS:47349090015
SN - 9783180920399
T3 - VDI Berichte
SP - 37
EP - 40
BT - Ist Syn TOP Smart Synthesis and Technologies for Organic Processes
ER -