Details
| Original language | English |
|---|---|
| Pages (from-to) | 9083-9098 |
| Number of pages | 16 |
| Journal | Journal of Chemical Physics |
| Volume | 114 |
| Issue number | 20 |
| Publication status | Published - 22 May 2001 |
Abstract
A mathematical model based on a single excitation mechanism was used for describing the formation of anisotropic chemical wave patterns in the NO+H2reaction on a Rh(110) surface. The experimentally measured bifurcation diagram was reproduced quantitavely to describe the ranges of the spatial patterns in the reaction. The state-independent anisotropy of surface diffusion site-blocking effects were accounted through coadsorbates for the diffusing species. The formation of travelling fragments, appearance of front geometries in the range of double metastability, parameter dependent anisotropy of reaction in the bistable range and that of target patterns in the excitable range were simulated.
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In: Journal of Chemical Physics, Vol. 114, No. 20, 22.05.2001, p. 9083-9098.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Modeling anisotropic chemical wave patterns in the NO+H2reaction on a Rh(110) surface
AU - Makeev, A.
AU - Hinz, M.
AU - Imbihl, R.
PY - 2001/5/22
Y1 - 2001/5/22
N2 - A mathematical model based on a single excitation mechanism was used for describing the formation of anisotropic chemical wave patterns in the NO+H2reaction on a Rh(110) surface. The experimentally measured bifurcation diagram was reproduced quantitavely to describe the ranges of the spatial patterns in the reaction. The state-independent anisotropy of surface diffusion site-blocking effects were accounted through coadsorbates for the diffusing species. The formation of travelling fragments, appearance of front geometries in the range of double metastability, parameter dependent anisotropy of reaction in the bistable range and that of target patterns in the excitable range were simulated.
AB - A mathematical model based on a single excitation mechanism was used for describing the formation of anisotropic chemical wave patterns in the NO+H2reaction on a Rh(110) surface. The experimentally measured bifurcation diagram was reproduced quantitavely to describe the ranges of the spatial patterns in the reaction. The state-independent anisotropy of surface diffusion site-blocking effects were accounted through coadsorbates for the diffusing species. The formation of travelling fragments, appearance of front geometries in the range of double metastability, parameter dependent anisotropy of reaction in the bistable range and that of target patterns in the excitable range were simulated.
UR - http://www.scopus.com/inward/record.url?scp=0035932867&partnerID=8YFLogxK
U2 - 10.1063/1.1362691
DO - 10.1063/1.1362691
M3 - Article
AN - SCOPUS:0035932867
VL - 114
SP - 9083
EP - 9098
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 20
ER -