Modeling a thermocell with proton exchange membrane and hydrogen electrodes

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Authors

  • T. Marquardt
  • G. Valadez Huerta
  • S. Kabelac

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Details

Original languageEnglish
Pages (from-to)19841-19850
Number of pages10
JournalInternational Journal of Hydrogen Energy
Volume43
Issue number43
Early online date1 Oct 2018
Publication statusPublished - 25 Oct 2018

Abstract

Direct conversion of thermal energy to electric energy with thermoelectric generators is an attractive technique to recover low-temperature heat. Thermoelectric generators based on galvanic cells (thermocells) provide promising results with respect to the Seebeck coefficient. In this study, based on the theory of non-equilibrium thermodynamics, we simulated a thermocell with hydrogen gas electrodes and a proton exchange membrane. We calculated a maximum power density of 1461 mW/m2 and a thermal efficiency of 2% relative to the Carnot efficiency for a cell operating with the same gas composition at both the anode and the cathode, but fully saturated at the anode. We predict a Seebeck coefficient in the range of 0.7–1.8 mV/K, higher than those of classical thermoelectric generators. The thermocell presented here provides promising values regarding the Seebeck coefficient.

Keywords

    Polymer electrolyte membrane, Thermocell, Thermogalvanic

ASJC Scopus subject areas

Sustainable Development Goals

Cite this

Modeling a thermocell with proton exchange membrane and hydrogen electrodes. / Marquardt, T.; Valadez Huerta, G.; Kabelac, S.
In: International Journal of Hydrogen Energy, Vol. 43, No. 43, 25.10.2018, p. 19841-19850.

Research output: Contribution to journalArticleResearchpeer review

Marquardt T, Valadez Huerta G, Kabelac S. Modeling a thermocell with proton exchange membrane and hydrogen electrodes. International Journal of Hydrogen Energy. 2018 Oct 25;43(43):19841-19850. Epub 2018 Oct 1. doi: 10.1016/j.ijhydene.2018.09.007
Marquardt, T. ; Valadez Huerta, G. ; Kabelac, S. / Modeling a thermocell with proton exchange membrane and hydrogen electrodes. In: International Journal of Hydrogen Energy. 2018 ; Vol. 43, No. 43. pp. 19841-19850.
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AU - Valadez Huerta, G.

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