Details
| Original language | English |
|---|---|
| Pages (from-to) | 563-566 |
| Number of pages | 4 |
| Journal | Synlett |
| Issue number | 4 |
| Publication status | Published - 21 Feb 2007 |
Abstract
m-Iodosylbenzoic acid selectively oxidizes primary and secondary alcohols to the respective carbonyl compounds in the presence of RuCl3 (0.5 mol%) at room temperature in aqueous acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form) or by simple extraction of the basic aqueous solution with water. The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion-exchange resin or from the basic aqueous solution by simple acidification with HCl.
Keywords
- Catalysis, Hypervalent iodine, m-iodosobenzoic acid, Oxidation, Scavenger
ASJC Scopus subject areas
- Chemistry(all)
- Organic Chemistry
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In: Synlett, No. 4, 21.02.2007, p. 563-566.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - m-iodosylbenzoic acid as a convenient recyclable reagent for highly efficient RuCl3-catalyzed oxidation of alcohols to carbonyl compounds
AU - Yusubov, Mekhman S.
AU - Gilmkhanova, Marina P.
AU - Zhdankin, Viktor V.
AU - Kirschning, Andreas
PY - 2007/2/21
Y1 - 2007/2/21
N2 - m-Iodosylbenzoic acid selectively oxidizes primary and secondary alcohols to the respective carbonyl compounds in the presence of RuCl3 (0.5 mol%) at room temperature in aqueous acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form) or by simple extraction of the basic aqueous solution with water. The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion-exchange resin or from the basic aqueous solution by simple acidification with HCl.
AB - m-Iodosylbenzoic acid selectively oxidizes primary and secondary alcohols to the respective carbonyl compounds in the presence of RuCl3 (0.5 mol%) at room temperature in aqueous acetonitrile. Separation of pure products is conveniently achieved by scavenging any aryl iodide by ion exchange with IRA-900 (hydroxide form) or by simple extraction of the basic aqueous solution with water. The reduced form of the reagent, m-iodobenzoic acid, can be easily recovered from the ion-exchange resin or from the basic aqueous solution by simple acidification with HCl.
KW - Catalysis
KW - Hypervalent iodine
KW - m-iodosobenzoic acid
KW - Oxidation
KW - Scavenger
UR - http://www.scopus.com/inward/record.url?scp=33947228565&partnerID=8YFLogxK
U2 - 10.1055/s-2007-970742
DO - 10.1055/s-2007-970742
M3 - Article
AN - SCOPUS:33947228565
SP - 563
EP - 566
JO - Synlett
JF - Synlett
SN - 0936-5214
IS - 4
ER -