Microwave Spectrum and Structure of the 1,2-Difluorobenzene-Argon van der Waals Complex

Research output: Contribution to journalArticleResearchpeer review

Authors

  • E. Jochims
  • J. U. Grabow
  • W. Stahl

External Research Organisations

  • Kiel University
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Details

Original languageEnglish
Pages (from-to)278-286
Number of pages9
JournalJournal of molecular spectroscopy
Volume158
Issue number2
Publication statusPublished - Apr 1993
Externally publishedYes

Abstract

Using a pulsed molecular beam microwave Fourier transform spectrometer, we measured the rotational spectrum of the 1,2-difluorobenzene-argon van der Waals complex in the range from 7 to 18 GHz. The rotational and centrifugal distortion constants were found to be A = l373.49072(9) MHz, B = 923.31007(10) MHz, C = 831.07477(6) MHz, ΔJ = 2.1104(8) kHz, ΔJK = 2.372(3) kHz, ΔK = -1.911(3) kHz. δJ = 0.4744(4) kHz, and δK = 1.785(9) kHz. The argon atom is placed 3.543 Å above the ring plane.

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Cite this

Microwave Spectrum and Structure of the 1,2-Difluorobenzene-Argon van der Waals Complex. / Jochims, E.; Grabow, J. U.; Stahl, W.
In: Journal of molecular spectroscopy, Vol. 158, No. 2, 04.1993, p. 278-286.

Research output: Contribution to journalArticleResearchpeer review

Jochims E, Grabow JU, Stahl W. Microwave Spectrum and Structure of the 1,2-Difluorobenzene-Argon van der Waals Complex. Journal of molecular spectroscopy. 1993 Apr;158(2):278-286. doi: 10.1006/jmsp.1993.1072
Jochims, E. ; Grabow, J. U. ; Stahl, W. / Microwave Spectrum and Structure of the 1,2-Difluorobenzene-Argon van der Waals Complex. In: Journal of molecular spectroscopy. 1993 ; Vol. 158, No. 2. pp. 278-286.
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abstract = "Using a pulsed molecular beam microwave Fourier transform spectrometer, we measured the rotational spectrum of the 1,2-difluorobenzene-argon van der Waals complex in the range from 7 to 18 GHz. The rotational and centrifugal distortion constants were found to be A = l373.49072(9) MHz, B = 923.31007(10) MHz, C = 831.07477(6) MHz, ΔJ = 2.1104(8) kHz, ΔJK = 2.372(3) kHz, ΔK = -1.911(3) kHz. δJ = 0.4744(4) kHz, and δK = 1.785(9) kHz. The argon atom is placed 3.543 {\AA} above the ring plane.",
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Download

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AU - Stahl, W.

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