Microwave spectra, hyperfine structure, and electric dipole moments for conformers i and ii of glycine

Research output: Contribution to journalArticleResearchpeer review

Authors

  • F. J. Lovas
  • Y. Kawashima
  • J. U. Grabow
  • R. D. Suenram
  • G. T. Fraser
  • E. Hirota

External Research Organisations

  • National Institute of Standards and Technology (NIST)
  • Kanagawa Institute of Technology
  • Graduate University for Advanced Studies
View graph of relations

Details

Original languageEnglish
Pages (from-to)L201-L204
JournalAstrophysical Journal
Volume455
Issue number2
Publication statusPublished - 20 Dec 1995

Abstract

A number of low-J rotational transitions have been measured for two conformations of the simplest amino acid, glycine, providing precise hyperfine transition frequencies and electric dipole moments for radioastronomy searches for glycine in interstellar clouds. Measurements were made between 12 and 25 GHz with a pulsed-nozzle, Fabry-Perot-cavity, Fourier transform microwave spectrometer equipped with either a heated nozzle or laser ablation-nozzle for vaporization of solid phase glycine. Nuclear quadrupole coupling constants were determined for both conformers from measurements of the hyperfine-split rotational transitions. The quadrupole coupling constants for conformer I are eQqaa = -1.208(9) MHz and eQqbb = -0.343(8) MHz and for conformer II are eQqaa = 1.773(2) MHz and eQqbb = -3.194(4) MHz. The dipole moment components of both conformers were determined to higher precision. We obtain µa = 3.039(10) X 10-30 C m [0.911(3)D] and ixb = 2.025(17) X 10-30 C m [0.607(5) D] for conformer I, and /xa = 17.92(11) X 10-30 C m [5.372(34)D] and /xb = 3.10(3) X 10-30 C m [0.93(1)D] for conformer II, where the uncertainties shown are 1 standard deviation.

Keywords

    ISM: molecules, Line: identification, Molecular data

ASJC Scopus subject areas

Cite this

Microwave spectra, hyperfine structure, and electric dipole moments for conformers i and ii of glycine. / Lovas, F. J.; Kawashima, Y.; Grabow, J. U. et al.
In: Astrophysical Journal, Vol. 455, No. 2, 20.12.1995, p. L201-L204.

Research output: Contribution to journalArticleResearchpeer review

Lovas, FJ, Kawashima, Y, Grabow, JU, Suenram, RD, Fraser, GT & Hirota, E 1995, 'Microwave spectra, hyperfine structure, and electric dipole moments for conformers i and ii of glycine', Astrophysical Journal, vol. 455, no. 2, pp. L201-L204. https://doi.org/10.1086/309844
Lovas, F. J., Kawashima, Y., Grabow, J. U., Suenram, R. D., Fraser, G. T., & Hirota, E. (1995). Microwave spectra, hyperfine structure, and electric dipole moments for conformers i and ii of glycine. Astrophysical Journal, 455(2), L201-L204. https://doi.org/10.1086/309844
Lovas FJ, Kawashima Y, Grabow JU, Suenram RD, Fraser GT, Hirota E. Microwave spectra, hyperfine structure, and electric dipole moments for conformers i and ii of glycine. Astrophysical Journal. 1995 Dec 20;455(2):L201-L204. doi: 10.1086/309844
Lovas, F. J. ; Kawashima, Y. ; Grabow, J. U. et al. / Microwave spectra, hyperfine structure, and electric dipole moments for conformers i and ii of glycine. In: Astrophysical Journal. 1995 ; Vol. 455, No. 2. pp. L201-L204.
Download
@article{1e08ecfa1f324317a368508fd5d0b450,
title = "Microwave spectra, hyperfine structure, and electric dipole moments for conformers i and ii of glycine",
abstract = "A number of low-J rotational transitions have been measured for two conformations of the simplest amino acid, glycine, providing precise hyperfine transition frequencies and electric dipole moments for radioastronomy searches for glycine in interstellar clouds. Measurements were made between 12 and 25 GHz with a pulsed-nozzle, Fabry-Perot-cavity, Fourier transform microwave spectrometer equipped with either a heated nozzle or laser ablation-nozzle for vaporization of solid phase glycine. Nuclear quadrupole coupling constants were determined for both conformers from measurements of the hyperfine-split rotational transitions. The quadrupole coupling constants for conformer I are eQqaa = -1.208(9) MHz and eQqbb = -0.343(8) MHz and for conformer II are eQqaa = 1.773(2) MHz and eQqbb = -3.194(4) MHz. The dipole moment components of both conformers were determined to higher precision. We obtain µa = 3.039(10) X 10-30 C m [0.911(3)D] and ixb = 2.025(17) X 10-30 C m [0.607(5) D] for conformer I, and /xa = 17.92(11) X 10-30 C m [5.372(34)D] and /xb = 3.10(3) X 10-30 C m [0.93(1)D] for conformer II, where the uncertainties shown are 1 standard deviation.",
keywords = "ISM: molecules, Line: identification, Molecular data",
author = "Lovas, {F. J.} and Y. Kawashima and Grabow, {J. U.} and Suenram, {R. D.} and Fraser, {G. T.} and E. Hirota",
note = "Funding Information: The present study was supported in part by Grant-in-Aid (No. 05044045) from the Japanese Ministry of Education, Science, and Culture International Scientific Research Program and a grant (GR 1344/1) from the Deutsche Forschun-gsyemeinschaft.",
year = "1995",
month = dec,
day = "20",
doi = "10.1086/309844",
language = "English",
volume = "455",
pages = "L201--L204",
journal = "Astrophysical Journal",
issn = "0004-637X",
publisher = "IOP Publishing Ltd.",
number = "2",

}

Download

TY - JOUR

T1 - Microwave spectra, hyperfine structure, and electric dipole moments for conformers i and ii of glycine

AU - Lovas, F. J.

AU - Kawashima, Y.

AU - Grabow, J. U.

AU - Suenram, R. D.

AU - Fraser, G. T.

AU - Hirota, E.

N1 - Funding Information: The present study was supported in part by Grant-in-Aid (No. 05044045) from the Japanese Ministry of Education, Science, and Culture International Scientific Research Program and a grant (GR 1344/1) from the Deutsche Forschun-gsyemeinschaft.

PY - 1995/12/20

Y1 - 1995/12/20

N2 - A number of low-J rotational transitions have been measured for two conformations of the simplest amino acid, glycine, providing precise hyperfine transition frequencies and electric dipole moments for radioastronomy searches for glycine in interstellar clouds. Measurements were made between 12 and 25 GHz with a pulsed-nozzle, Fabry-Perot-cavity, Fourier transform microwave spectrometer equipped with either a heated nozzle or laser ablation-nozzle for vaporization of solid phase glycine. Nuclear quadrupole coupling constants were determined for both conformers from measurements of the hyperfine-split rotational transitions. The quadrupole coupling constants for conformer I are eQqaa = -1.208(9) MHz and eQqbb = -0.343(8) MHz and for conformer II are eQqaa = 1.773(2) MHz and eQqbb = -3.194(4) MHz. The dipole moment components of both conformers were determined to higher precision. We obtain µa = 3.039(10) X 10-30 C m [0.911(3)D] and ixb = 2.025(17) X 10-30 C m [0.607(5) D] for conformer I, and /xa = 17.92(11) X 10-30 C m [5.372(34)D] and /xb = 3.10(3) X 10-30 C m [0.93(1)D] for conformer II, where the uncertainties shown are 1 standard deviation.

AB - A number of low-J rotational transitions have been measured for two conformations of the simplest amino acid, glycine, providing precise hyperfine transition frequencies and electric dipole moments for radioastronomy searches for glycine in interstellar clouds. Measurements were made between 12 and 25 GHz with a pulsed-nozzle, Fabry-Perot-cavity, Fourier transform microwave spectrometer equipped with either a heated nozzle or laser ablation-nozzle for vaporization of solid phase glycine. Nuclear quadrupole coupling constants were determined for both conformers from measurements of the hyperfine-split rotational transitions. The quadrupole coupling constants for conformer I are eQqaa = -1.208(9) MHz and eQqbb = -0.343(8) MHz and for conformer II are eQqaa = 1.773(2) MHz and eQqbb = -3.194(4) MHz. The dipole moment components of both conformers were determined to higher precision. We obtain µa = 3.039(10) X 10-30 C m [0.911(3)D] and ixb = 2.025(17) X 10-30 C m [0.607(5) D] for conformer I, and /xa = 17.92(11) X 10-30 C m [5.372(34)D] and /xb = 3.10(3) X 10-30 C m [0.93(1)D] for conformer II, where the uncertainties shown are 1 standard deviation.

KW - ISM: molecules

KW - Line: identification

KW - Molecular data

UR - http://www.scopus.com/inward/record.url?scp=0029471702&partnerID=8YFLogxK

U2 - 10.1086/309844

DO - 10.1086/309844

M3 - Article

AN - SCOPUS:0029471702

VL - 455

SP - L201-L204

JO - Astrophysical Journal

JF - Astrophysical Journal

SN - 0004-637X

IS - 2

ER -