Details
Original language | English |
---|---|
Pages (from-to) | 225-231 |
Number of pages | 7 |
Journal | Colloid and polymer science |
Volume | 286 |
Issue number | 2 |
Publication status | Published - 9 Oct 2007 |
Abstract
Patterned films with hexagonal structures were prepared by photochemical grafting of hydrophobic poly(acrylic acid 2-ethyl-hexylester) (PEHAA) as barrier and poly(ethylene imine) (PEI) as reaction area. The films have been characterized by ellipsometry, contact angle measurements, and scanning electron microscopy (SEM). These patterned films have been used in silica mineralization experiments by dipping them into a silica precursor solution. Silica deposition occurs only in PEI-coated areas, resulting in regular arrays of lens-shaped silica particles. The deposited silica was investigated by SEM and atomic force microscopy (AFM).
Keywords
- Photochemical grafting, Poly(ethyleneimine), Silica deposition, Surface patterning
ASJC Scopus subject areas
- Chemistry(all)
- Physical and Theoretical Chemistry
- Materials Science(all)
- Polymers and Plastics
- Chemical Engineering(all)
- Colloid and Surface Chemistry
- Materials Science(all)
- Materials Chemistry
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In: Colloid and polymer science, Vol. 286, No. 2, 09.10.2007, p. 225-231.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Microstructured reaction areas for the deposition of silica
AU - Helmecke, Olaf
AU - Hirsch, Alexander
AU - Behrens, Peter
AU - Menzel, Henning
N1 - Funding information: The authors would like to thank Prof. A. Waag and M. Karsten (Institute of Semiconductor Technology, Braunschweig University of Technology) for the preparation of the mask and A. Scherbarth for SEM measurements. This work was supported in the scope of the Priority Research Program 1117 “Principles of Biomineralization” by the Deutsche Forschungsgemeinschaft (DFG).
PY - 2007/10/9
Y1 - 2007/10/9
N2 - Patterned films with hexagonal structures were prepared by photochemical grafting of hydrophobic poly(acrylic acid 2-ethyl-hexylester) (PEHAA) as barrier and poly(ethylene imine) (PEI) as reaction area. The films have been characterized by ellipsometry, contact angle measurements, and scanning electron microscopy (SEM). These patterned films have been used in silica mineralization experiments by dipping them into a silica precursor solution. Silica deposition occurs only in PEI-coated areas, resulting in regular arrays of lens-shaped silica particles. The deposited silica was investigated by SEM and atomic force microscopy (AFM).
AB - Patterned films with hexagonal structures were prepared by photochemical grafting of hydrophobic poly(acrylic acid 2-ethyl-hexylester) (PEHAA) as barrier and poly(ethylene imine) (PEI) as reaction area. The films have been characterized by ellipsometry, contact angle measurements, and scanning electron microscopy (SEM). These patterned films have been used in silica mineralization experiments by dipping them into a silica precursor solution. Silica deposition occurs only in PEI-coated areas, resulting in regular arrays of lens-shaped silica particles. The deposited silica was investigated by SEM and atomic force microscopy (AFM).
KW - Photochemical grafting
KW - Poly(ethyleneimine)
KW - Silica deposition
KW - Surface patterning
UR - http://www.scopus.com/inward/record.url?scp=38649135430&partnerID=8YFLogxK
U2 - 10.1007/s00396-007-1773-y
DO - 10.1007/s00396-007-1773-y
M3 - Article
AN - SCOPUS:38649135430
VL - 286
SP - 225
EP - 231
JO - Colloid and polymer science
JF - Colloid and polymer science
SN - 0303-402X
IS - 2
ER -