Microstructure of thin film platinum electrodes on yttrium stabilized zirconia prepared by sputter deposition

Research output: Contribution to journalArticleResearchpeer review

Authors

  • Arafat Toghan
  • M. Khodari
  • F. Steinbach
  • R. Imbihl

External Research Organisations

  • South Valley University, Egypt
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Details

Original languageEnglish
Pages (from-to)8139-8143
Number of pages5
JournalTHIN SOLID FILMS
Volume519
Issue number22
Early online date15 Jun 2011
Publication statusPublished - 1 Sept 2011

Abstract

(111) oriented thin film Pt electrodes were prepared on single crystals of yttrium-stabilized zirconia (YSZ) by sputter deposition of platinum. The electrodes were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), X-ray diffraction (XRD), energy-dispersive X-ray analysis (EDX), atomic force microscopy (AFM) and by profilometry. SEM images of the as-sputtered platinum film show a compact amorphous Pt film covering uniformly the substrate. Upon annealing at 1123 K, gaps and pores at the interface develop leading to a partial dewetting of the Pt film. Increasing the annealing temperature to 1373 K transforms the polycrystalline Pt film into single crystalline grains exhibiting a (111) orientation towards the substrate.

Keywords

    Dewetting, Interface, Platinum, Sputter deposition, Yttrium-stabilized zirconia

ASJC Scopus subject areas

Cite this

Microstructure of thin film platinum electrodes on yttrium stabilized zirconia prepared by sputter deposition. / Toghan, Arafat; Khodari, M.; Steinbach, F. et al.
In: THIN SOLID FILMS, Vol. 519, No. 22, 01.09.2011, p. 8139-8143.

Research output: Contribution to journalArticleResearchpeer review

Toghan A, Khodari M, Steinbach F, Imbihl R. Microstructure of thin film platinum electrodes on yttrium stabilized zirconia prepared by sputter deposition. THIN SOLID FILMS. 2011 Sept 1;519(22):8139-8143. Epub 2011 Jun 15. doi: 10.1016/j.tsf.2011.06.018
Toghan, Arafat ; Khodari, M. ; Steinbach, F. et al. / Microstructure of thin film platinum electrodes on yttrium stabilized zirconia prepared by sputter deposition. In: THIN SOLID FILMS. 2011 ; Vol. 519, No. 22. pp. 8139-8143.
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abstract = "(111) oriented thin film Pt electrodes were prepared on single crystals of yttrium-stabilized zirconia (YSZ) by sputter deposition of platinum. The electrodes were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), X-ray diffraction (XRD), energy-dispersive X-ray analysis (EDX), atomic force microscopy (AFM) and by profilometry. SEM images of the as-sputtered platinum film show a compact amorphous Pt film covering uniformly the substrate. Upon annealing at 1123 K, gaps and pores at the interface develop leading to a partial dewetting of the Pt film. Increasing the annealing temperature to 1373 K transforms the polycrystalline Pt film into single crystalline grains exhibiting a (111) orientation towards the substrate.",
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AU - Toghan, Arafat

AU - Khodari, M.

AU - Steinbach, F.

AU - Imbihl, R.

N1 - Funding Information: This work was supported by the German Research Foundation (DFG). A. T. thanks the Egyptian Ministry of Higher Education for providing him a doctoral scholarship. The authors are indebted to. V. Yarovyi and K. Efimov for assistance with the TEM and XRD measurements.

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N2 - (111) oriented thin film Pt electrodes were prepared on single crystals of yttrium-stabilized zirconia (YSZ) by sputter deposition of platinum. The electrodes were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), X-ray diffraction (XRD), energy-dispersive X-ray analysis (EDX), atomic force microscopy (AFM) and by profilometry. SEM images of the as-sputtered platinum film show a compact amorphous Pt film covering uniformly the substrate. Upon annealing at 1123 K, gaps and pores at the interface develop leading to a partial dewetting of the Pt film. Increasing the annealing temperature to 1373 K transforms the polycrystalline Pt film into single crystalline grains exhibiting a (111) orientation towards the substrate.

AB - (111) oriented thin film Pt electrodes were prepared on single crystals of yttrium-stabilized zirconia (YSZ) by sputter deposition of platinum. The electrodes were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), X-ray diffraction (XRD), energy-dispersive X-ray analysis (EDX), atomic force microscopy (AFM) and by profilometry. SEM images of the as-sputtered platinum film show a compact amorphous Pt film covering uniformly the substrate. Upon annealing at 1123 K, gaps and pores at the interface develop leading to a partial dewetting of the Pt film. Increasing the annealing temperature to 1373 K transforms the polycrystalline Pt film into single crystalline grains exhibiting a (111) orientation towards the substrate.

KW - Dewetting

KW - Interface

KW - Platinum

KW - Sputter deposition

KW - Yttrium-stabilized zirconia

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