Light-induced lifetime degradation in high-performance multicrystalline silicon: Detailed kinetics of the defect activation

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Original languageEnglish
Pages (from-to)2-5
Number of pages4
JournalSolar Energy Materials and Solar Cells
Volume173
Publication statusPublished - Dec 2017

Abstract

We examine the defect activation kinetics in block-cast high-performance multicrystalline silicon (HP mc-Si) under illumination at elevated temperature. Our lifetime analysis shows that the observed light-induced lifetime degradation consists of two separate stages: a fast stage followed by a slow stage. Our experiments reveal that both degradation stages can be fitted using a sum of two exponential decay functions. The resulting degradation rate constants depend both on the temperature and the light intensity applied during degradation. For the fast component, we determine an activation energy of (0.89 ± 0.04) eV from an Arrhenius plot of the degradation rate and for the slow component we determine a value of (0.94 ± 0.06) eV. The activation energies are relatively large, leading to a very pronounced dependence of the degradation rates on temperature. We also observe that both degradation rates show a linear dependence on the applied light intensity during degradation in the examined intensity range between 0.25 and 1.5 suns.

Keywords

    Carrier lifetime, Degradation, Multicrystalline silicon

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Light-induced lifetime degradation in high-performance multicrystalline silicon: Detailed kinetics of the defect activation. / Bredemeier, Dennis; Walter, Dominic C.; Schmidt, Jan.
In: Solar Energy Materials and Solar Cells, Vol. 173, 12.2017, p. 2-5.

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keywords = "Carrier lifetime, Degradation, Multicrystalline silicon",
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T1 - Light-induced lifetime degradation in high-performance multicrystalline silicon: Detailed kinetics of the defect activation

AU - Bredemeier, Dennis

AU - Walter, Dominic C.

AU - Schmidt, Jan

N1 - Publisher Copyright: © 2017 Elsevier B.V.

PY - 2017/12

Y1 - 2017/12

N2 - We examine the defect activation kinetics in block-cast high-performance multicrystalline silicon (HP mc-Si) under illumination at elevated temperature. Our lifetime analysis shows that the observed light-induced lifetime degradation consists of two separate stages: a fast stage followed by a slow stage. Our experiments reveal that both degradation stages can be fitted using a sum of two exponential decay functions. The resulting degradation rate constants depend both on the temperature and the light intensity applied during degradation. For the fast component, we determine an activation energy of (0.89 ± 0.04) eV from an Arrhenius plot of the degradation rate and for the slow component we determine a value of (0.94 ± 0.06) eV. The activation energies are relatively large, leading to a very pronounced dependence of the degradation rates on temperature. We also observe that both degradation rates show a linear dependence on the applied light intensity during degradation in the examined intensity range between 0.25 and 1.5 suns.

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KW - Carrier lifetime

KW - Degradation

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