Laser-induced growth and self-organization of silver nanoparticles in colloidal polymers

Research output: Contribution to journalArticleResearchpeer review

Authors

  • V. N. Bagratashvili
  • A. O. Rybaltovskii
  • S. S. Ilyukhin
  • O. L. Zakharkina
  • V. Ya Panchenko
  • P. S. Timashev
  • M. A. Timofeev
  • S. I. Tsypina
  • V. I. Yusupov
  • A. B. Evlyukhin
  • B. N. Chichkov

External Research Organisations

  • Russian Academy of Sciences (RAS)
  • Lomonosov Moscow State University
  • Laser Zentrum Hannover e.V. (LZH)
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Details

Original languageEnglish
Article number126001
JournalLaser physics
Volume24
Issue number12
Publication statusPublished - 1 Dec 2014
Externally publishedYes

Abstract

The effects of CW laser radiation with a wavelength of λ = 532 nm on ethyl methacrylate copolymer films doped with the Ag(hfac)COD silver precursor were studied. Laser heating of the polymer composite (up to 150-170 °C), induced by the formation of highly absorbing silver nanoparticles (NPs), brings about an accelerated photo-thermochemical decomposition of the precursor, plastification of the polymer, local transition of the composite matrix to a colloidal state and intense thermocapillary convection in the dynamic active colloid formed. As a result, a directed transport of silver NPs from the center of the laser beam to its periphery takes place, leading to the formation of a ring structure with a very high concentration of silver NPs.

Keywords

    dynamic active colloid, polymer composite, silver nanoparticles, thermocapillary convection

ASJC Scopus subject areas

Cite this

Laser-induced growth and self-organization of silver nanoparticles in colloidal polymers. / Bagratashvili, V. N.; Rybaltovskii, A. O.; Ilyukhin, S. S. et al.
In: Laser physics, Vol. 24, No. 12, 126001, 01.12.2014.

Research output: Contribution to journalArticleResearchpeer review

Bagratashvili, VN, Rybaltovskii, AO, Ilyukhin, SS, Zakharkina, OL, Panchenko, VY, Timashev, PS, Timofeev, MA, Tsypina, SI, Yusupov, VI, Evlyukhin, AB & Chichkov, BN 2014, 'Laser-induced growth and self-organization of silver nanoparticles in colloidal polymers', Laser physics, vol. 24, no. 12, 126001. https://doi.org/10.1088/1054-660x/24/12/126001
Bagratashvili, V. N., Rybaltovskii, A. O., Ilyukhin, S. S., Zakharkina, O. L., Panchenko, V. Y., Timashev, P. S., Timofeev, M. A., Tsypina, S. I., Yusupov, V. I., Evlyukhin, A. B., & Chichkov, B. N. (2014). Laser-induced growth and self-organization of silver nanoparticles in colloidal polymers. Laser physics, 24(12), Article 126001. https://doi.org/10.1088/1054-660x/24/12/126001
Bagratashvili VN, Rybaltovskii AO, Ilyukhin SS, Zakharkina OL, Panchenko VY, Timashev PS et al. Laser-induced growth and self-organization of silver nanoparticles in colloidal polymers. Laser physics. 2014 Dec 1;24(12):126001. doi: 10.1088/1054-660x/24/12/126001
Bagratashvili, V. N. ; Rybaltovskii, A. O. ; Ilyukhin, S. S. et al. / Laser-induced growth and self-organization of silver nanoparticles in colloidal polymers. In: Laser physics. 2014 ; Vol. 24, No. 12.
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abstract = "The effects of CW laser radiation with a wavelength of λ = 532 nm on ethyl methacrylate copolymer films doped with the Ag(hfac)COD silver precursor were studied. Laser heating of the polymer composite (up to 150-170 °C), induced by the formation of highly absorbing silver nanoparticles (NPs), brings about an accelerated photo-thermochemical decomposition of the precursor, plastification of the polymer, local transition of the composite matrix to a colloidal state and intense thermocapillary convection in the dynamic active colloid formed. As a result, a directed transport of silver NPs from the center of the laser beam to its periphery takes place, leading to the formation of a ring structure with a very high concentration of silver NPs.",
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T1 - Laser-induced growth and self-organization of silver nanoparticles in colloidal polymers

AU - Bagratashvili, V. N.

AU - Rybaltovskii, A. O.

AU - Ilyukhin, S. S.

AU - Zakharkina, O. L.

AU - Panchenko, V. Ya

AU - Timashev, P. S.

AU - Timofeev, M. A.

AU - Tsypina, S. I.

AU - Yusupov, V. I.

AU - Evlyukhin, A. B.

AU - Chichkov, B. N.

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N2 - The effects of CW laser radiation with a wavelength of λ = 532 nm on ethyl methacrylate copolymer films doped with the Ag(hfac)COD silver precursor were studied. Laser heating of the polymer composite (up to 150-170 °C), induced by the formation of highly absorbing silver nanoparticles (NPs), brings about an accelerated photo-thermochemical decomposition of the precursor, plastification of the polymer, local transition of the composite matrix to a colloidal state and intense thermocapillary convection in the dynamic active colloid formed. As a result, a directed transport of silver NPs from the center of the laser beam to its periphery takes place, leading to the formation of a ring structure with a very high concentration of silver NPs.

AB - The effects of CW laser radiation with a wavelength of λ = 532 nm on ethyl methacrylate copolymer films doped with the Ag(hfac)COD silver precursor were studied. Laser heating of the polymer composite (up to 150-170 °C), induced by the formation of highly absorbing silver nanoparticles (NPs), brings about an accelerated photo-thermochemical decomposition of the precursor, plastification of the polymer, local transition of the composite matrix to a colloidal state and intense thermocapillary convection in the dynamic active colloid formed. As a result, a directed transport of silver NPs from the center of the laser beam to its periphery takes place, leading to the formation of a ring structure with a very high concentration of silver NPs.

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KW - polymer composite

KW - silver nanoparticles

KW - thermocapillary convection

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