Laboratory method for determining immobile soil water content and mass exchange coefficient

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Original languageEnglish
Pages (from-to)332-338
Number of pages7
JournalJournal of Plant Nutrition and Soil Science
Volume165
Issue number3
Publication statusPublished - 1 Jun 2002

Abstract

Preferential flow in soil can enhance the leaching of agricultural chemicals. In a number of studies it has been shown that the mobile-immobile solute transport model (MIM) is a useful tool to characterize preferential flow. In the present study, a new laboratory method for determining the MIM parameters θm and θim (mobile and immobile water content), as well as a (mass transfer coefficient), is developed. The computations are uncomplicated and the method requires only simple equipment. It is applied to short, undisturbed soil columns. Measured values ranged from 0.11 to 0,27 for θim θ-1 and from 0.015 h -1 to 0.034 h-1 for α for an Iowan soil (Nicollet silt loam). For two sandy Eutric Gleysols from Germany, low values for θim θ-1 from 0.04 to 0.07 and from 0.001 h-1 to 0.008 h-1 for α were determined. Although the new method is a flow-interruption technique, values for the Nicollet silt loam compare well with those from conventional leaching experiments. Values for the Eutric Gleysols agree with the observation that these soils were poorly structured. Because the new method does not assume negligible dispersion, it is applicable to a wider range of soils and boundary conditions than comparable approaches. We conclude that the new method provides parameter values that are suited to describe non-equilibrium solute transport.

Keywords

    Agrochemical leaching, Mass exchange coefficient, Mobile-immobile soil water, Preferential flow, Solute transport

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Cite this

Laboratory method for determining immobile soil water content and mass exchange coefficient. / Ilsemann, Jan; Van Der Ploeg, Rienk R.; Horton, Robert et al.
In: Journal of Plant Nutrition and Soil Science, Vol. 165, No. 3, 01.06.2002, p. 332-338.

Research output: Contribution to journalArticleResearchpeer review

Ilsemann J, Van Der Ploeg RR, Horton R, Bachmann J. Laboratory method for determining immobile soil water content and mass exchange coefficient. Journal of Plant Nutrition and Soil Science. 2002 Jun 1;165(3):332-338. doi: 10.1002/1522-2624(200206)165:3<332::AID-JPLN332>3.0.CO;2-M
Ilsemann, Jan ; Van Der Ploeg, Rienk R. ; Horton, Robert et al. / Laboratory method for determining immobile soil water content and mass exchange coefficient. In: Journal of Plant Nutrition and Soil Science. 2002 ; Vol. 165, No. 3. pp. 332-338.
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AU - Ilsemann, Jan

AU - Van Der Ploeg, Rienk R.

AU - Horton, Robert

AU - Bachmann, Jörg

N1 - Copyright: Copyright 2008 Elsevier B.V., All rights reserved.

PY - 2002/6/1

Y1 - 2002/6/1

N2 - Preferential flow in soil can enhance the leaching of agricultural chemicals. In a number of studies it has been shown that the mobile-immobile solute transport model (MIM) is a useful tool to characterize preferential flow. In the present study, a new laboratory method for determining the MIM parameters θm and θim (mobile and immobile water content), as well as a (mass transfer coefficient), is developed. The computations are uncomplicated and the method requires only simple equipment. It is applied to short, undisturbed soil columns. Measured values ranged from 0.11 to 0,27 for θim θ-1 and from 0.015 h -1 to 0.034 h-1 for α for an Iowan soil (Nicollet silt loam). For two sandy Eutric Gleysols from Germany, low values for θim θ-1 from 0.04 to 0.07 and from 0.001 h-1 to 0.008 h-1 for α were determined. Although the new method is a flow-interruption technique, values for the Nicollet silt loam compare well with those from conventional leaching experiments. Values for the Eutric Gleysols agree with the observation that these soils were poorly structured. Because the new method does not assume negligible dispersion, it is applicable to a wider range of soils and boundary conditions than comparable approaches. We conclude that the new method provides parameter values that are suited to describe non-equilibrium solute transport.

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