Kinetics of pressure relaxation in a compressed alkali borosilicate glass

Research output: Contribution to journalArticleResearchpeer review

Authors

  • L. Wondraczek
  • S. Krolikowski
  • H. Behrens

Research Organisations

External Research Organisations

  • Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU Erlangen-Nürnberg)
View graph of relations

Details

Original languageEnglish
Pages (from-to)1859-1862
Number of pages4
JournalJournal of non-crystalline solids
Volume356
Issue number35-36
Early online date24 Jul 2010
Publication statusPublished - 1 Aug 2010

Abstract

Isothermal relaxation experiments were conducted on a mildly densified alkali borosilicate glass with an initial fictive pressure of 500 MPa. Annealing under ambient pressure at various temperatures below the glass transition leads to a gradually decreasing fictive pressure, monitored by ex situ density measurements. Relaxation times are extracted from the temporal evolution of the corresponding reaction coordinate, and an activation energy of 761 ± 40 kJ/mol is found. The timescale of pressure relaxation is similar to that of shear relaxation, but the pressure-dependence of viscosity must be considered for this assessment.

Keywords

    Pressure-effects, Relaxation, Viscosity

ASJC Scopus subject areas

Cite this

Kinetics of pressure relaxation in a compressed alkali borosilicate glass. / Wondraczek, L.; Krolikowski, S.; Behrens, H.
In: Journal of non-crystalline solids, Vol. 356, No. 35-36, 01.08.2010, p. 1859-1862.

Research output: Contribution to journalArticleResearchpeer review

Wondraczek L, Krolikowski S, Behrens H. Kinetics of pressure relaxation in a compressed alkali borosilicate glass. Journal of non-crystalline solids. 2010 Aug 1;356(35-36):1859-1862. Epub 2010 Jul 24. doi: 10.1016/j.jnoncrysol.2010.06.009
Wondraczek, L. ; Krolikowski, S. ; Behrens, H. / Kinetics of pressure relaxation in a compressed alkali borosilicate glass. In: Journal of non-crystalline solids. 2010 ; Vol. 356, No. 35-36. pp. 1859-1862.
Download
@article{6e9f05e515e546cb8d051f2ff2af1ced,
title = "Kinetics of pressure relaxation in a compressed alkali borosilicate glass",
abstract = "Isothermal relaxation experiments were conducted on a mildly densified alkali borosilicate glass with an initial fictive pressure of 500 MPa. Annealing under ambient pressure at various temperatures below the glass transition leads to a gradually decreasing fictive pressure, monitored by ex situ density measurements. Relaxation times are extracted from the temporal evolution of the corresponding reaction coordinate, and an activation energy of 761 ± 40 kJ/mol is found. The timescale of pressure relaxation is similar to that of shear relaxation, but the pressure-dependence of viscosity must be considered for this assessment.",
keywords = "Pressure-effects, Relaxation, Viscosity",
author = "L. Wondraczek and S. Krolikowski and H. Behrens",
note = "Funding Information: Financial support by the Deutsche Forschungsgemeinschaft (DFG) under grant no. WO 1220/3-1 is gratefully acknowledged.",
year = "2010",
month = aug,
day = "1",
doi = "10.1016/j.jnoncrysol.2010.06.009",
language = "English",
volume = "356",
pages = "1859--1862",
journal = "Journal of non-crystalline solids",
issn = "0022-3093",
publisher = "Elsevier",
number = "35-36",

}

Download

TY - JOUR

T1 - Kinetics of pressure relaxation in a compressed alkali borosilicate glass

AU - Wondraczek, L.

AU - Krolikowski, S.

AU - Behrens, H.

N1 - Funding Information: Financial support by the Deutsche Forschungsgemeinschaft (DFG) under grant no. WO 1220/3-1 is gratefully acknowledged.

PY - 2010/8/1

Y1 - 2010/8/1

N2 - Isothermal relaxation experiments were conducted on a mildly densified alkali borosilicate glass with an initial fictive pressure of 500 MPa. Annealing under ambient pressure at various temperatures below the glass transition leads to a gradually decreasing fictive pressure, monitored by ex situ density measurements. Relaxation times are extracted from the temporal evolution of the corresponding reaction coordinate, and an activation energy of 761 ± 40 kJ/mol is found. The timescale of pressure relaxation is similar to that of shear relaxation, but the pressure-dependence of viscosity must be considered for this assessment.

AB - Isothermal relaxation experiments were conducted on a mildly densified alkali borosilicate glass with an initial fictive pressure of 500 MPa. Annealing under ambient pressure at various temperatures below the glass transition leads to a gradually decreasing fictive pressure, monitored by ex situ density measurements. Relaxation times are extracted from the temporal evolution of the corresponding reaction coordinate, and an activation energy of 761 ± 40 kJ/mol is found. The timescale of pressure relaxation is similar to that of shear relaxation, but the pressure-dependence of viscosity must be considered for this assessment.

KW - Pressure-effects

KW - Relaxation

KW - Viscosity

UR - http://www.scopus.com/inward/record.url?scp=77957904139&partnerID=8YFLogxK

U2 - 10.1016/j.jnoncrysol.2010.06.009

DO - 10.1016/j.jnoncrysol.2010.06.009

M3 - Article

AN - SCOPUS:77957904139

VL - 356

SP - 1859

EP - 1862

JO - Journal of non-crystalline solids

JF - Journal of non-crystalline solids

SN - 0022-3093

IS - 35-36

ER -