Details
| Original language | English |
|---|---|
| Pages (from-to) | 4713-4718 |
| Number of pages | 6 |
| Journal | Journal of non-crystalline solids |
| Volume | 354 |
| Issue number | 42-44 |
| Publication status | Published - 26 Aug 2008 |
Abstract
The effect of hydration on the kinetic fragility of soda-lime-silica glasses was investigated by viscometry in the glass transition range. Water-bearing glasses were prepared from industrial float glass (FG) and a ternary model glass (NCS = 16Na2O 10CaO 74SiO2 in mol%) by bubbling steam through the melt at 1480 °C and up to 7 bar. Additionally, a sodium borosilicate glass (NBS = 16Na2O 10B2O3 74SiO2 in mol%) was hydrated under equal conditions. As detected by infrared spectroscopy water dissolves in the glasses exclusively as OH-groups. The hydration resulted in a total water content CW up to ≈ 0.2 wt% for FG, NCS and NBS glasses. Kinetic fragility, expressed by the steepness index m, was determined from the temperature dependence of η at the glass transition. Viscosity data from previous studies on hydrous float glasses (CW > 1 wt%) were surveyed together with literature data on the (H2O)-Na2O-CaO-SiO2, (H2O)-Na2O-SiO2 and (H2O)-SiO2 systems to expand the range of water concentration and bulk composition. We could demonstrate that m decreases for all glasses although water is dissolved as OH and should depolymerize the network. An empirical equation of the general type m = a - b logCW where a, b are fitting parameters, enables m to be predicted, for each glass series as function of the water content CW. The enlarged data base shows that the parameter B of the Arrhenius viscosity-temperature relation decreases much stronger than the isokom temperature at the glass transition.
Keywords
- Fragility, Soda-lime-silica, Viscosity, Water in glass
ASJC Scopus subject areas
- Materials Science(all)
- Electronic, Optical and Magnetic Materials
- Materials Science(all)
- Ceramics and Composites
- Physics and Astronomy(all)
- Condensed Matter Physics
- Materials Science(all)
- Materials Chemistry
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In: Journal of non-crystalline solids, Vol. 354, No. 42-44, 26.08.2008, p. 4713-4718.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Kinetic fragility of hydrous soda-lime-silica glasses
AU - Deubener, J.
AU - Behrens, H.
AU - Müller, R.
AU - Zietka, S.
AU - Reinsch, S.
N1 - Funding Information: The research was supported by the German Research Foundation DFG under Grants De 598/4, Be 1720/9 and Mu 963/4.
PY - 2008/8/26
Y1 - 2008/8/26
N2 - The effect of hydration on the kinetic fragility of soda-lime-silica glasses was investigated by viscometry in the glass transition range. Water-bearing glasses were prepared from industrial float glass (FG) and a ternary model glass (NCS = 16Na2O 10CaO 74SiO2 in mol%) by bubbling steam through the melt at 1480 °C and up to 7 bar. Additionally, a sodium borosilicate glass (NBS = 16Na2O 10B2O3 74SiO2 in mol%) was hydrated under equal conditions. As detected by infrared spectroscopy water dissolves in the glasses exclusively as OH-groups. The hydration resulted in a total water content CW up to ≈ 0.2 wt% for FG, NCS and NBS glasses. Kinetic fragility, expressed by the steepness index m, was determined from the temperature dependence of η at the glass transition. Viscosity data from previous studies on hydrous float glasses (CW > 1 wt%) were surveyed together with literature data on the (H2O)-Na2O-CaO-SiO2, (H2O)-Na2O-SiO2 and (H2O)-SiO2 systems to expand the range of water concentration and bulk composition. We could demonstrate that m decreases for all glasses although water is dissolved as OH and should depolymerize the network. An empirical equation of the general type m = a - b logCW where a, b are fitting parameters, enables m to be predicted, for each glass series as function of the water content CW. The enlarged data base shows that the parameter B of the Arrhenius viscosity-temperature relation decreases much stronger than the isokom temperature at the glass transition.
AB - The effect of hydration on the kinetic fragility of soda-lime-silica glasses was investigated by viscometry in the glass transition range. Water-bearing glasses were prepared from industrial float glass (FG) and a ternary model glass (NCS = 16Na2O 10CaO 74SiO2 in mol%) by bubbling steam through the melt at 1480 °C and up to 7 bar. Additionally, a sodium borosilicate glass (NBS = 16Na2O 10B2O3 74SiO2 in mol%) was hydrated under equal conditions. As detected by infrared spectroscopy water dissolves in the glasses exclusively as OH-groups. The hydration resulted in a total water content CW up to ≈ 0.2 wt% for FG, NCS and NBS glasses. Kinetic fragility, expressed by the steepness index m, was determined from the temperature dependence of η at the glass transition. Viscosity data from previous studies on hydrous float glasses (CW > 1 wt%) were surveyed together with literature data on the (H2O)-Na2O-CaO-SiO2, (H2O)-Na2O-SiO2 and (H2O)-SiO2 systems to expand the range of water concentration and bulk composition. We could demonstrate that m decreases for all glasses although water is dissolved as OH and should depolymerize the network. An empirical equation of the general type m = a - b logCW where a, b are fitting parameters, enables m to be predicted, for each glass series as function of the water content CW. The enlarged data base shows that the parameter B of the Arrhenius viscosity-temperature relation decreases much stronger than the isokom temperature at the glass transition.
KW - Fragility
KW - Soda-lime-silica
KW - Viscosity
KW - Water in glass
UR - http://www.scopus.com/inward/record.url?scp=53249154657&partnerID=8YFLogxK
U2 - 10.1016/j.jnoncrysol.2008.04.021
DO - 10.1016/j.jnoncrysol.2008.04.021
M3 - Article
AN - SCOPUS:53249154657
VL - 354
SP - 4713
EP - 4718
JO - Journal of non-crystalline solids
JF - Journal of non-crystalline solids
SN - 0022-3093
IS - 42-44
ER -