Details
| Original language | English |
|---|---|
| Pages (from-to) | 337-343 |
| Number of pages | 7 |
| Journal | Radiochimica Acta |
| Volume | 90 |
| Issue number | 6 |
| Publication status | Published - 2002 |
| Externally published | Yes |
Abstract
Gas-phase ion chemistry in a Penning trap has been explored for future experiments on the chemical properties of the heaviest elements. The Mainz Cluster Trap, a Penning trap experiment devoted to metal cluster research, has served as a model apparatus for SHIPTRAP which is being installed behind the velocity filter SHIP (Separator for Heavy Ion reaction Products) at the Gesellschaft für Schwerionenforschung (GSI) at Darmstadt. The reactions of stored Ru+ and Os+ with oxygen have been studied and the reaction products MO+ and MO2+ (M = Ru, Os) have been observed. The corresponding rate constants have been measured and the results are discussed with respect to future studies of similar ion-molecule reactions of the element 108 (hassium) in SHIPTRAP.
Keywords
- Chemistry of superheavy elements, Ion-molecule reactions, Penning trap, Rul, Os, Ti, Zr
ASJC Scopus subject areas
- Chemistry(all)
- Physical and Theoretical Chemistry
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In: Radiochimica Acta, Vol. 90, No. 6, 2002, p. 337-343.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Ion-molecule reactions of Ru+ and Os+ with oxygen in a Penning trap
AU - Rieth, U.
AU - Herlert, A.
AU - Kratz, J. V.
AU - Schweikhard, L.
AU - Vogel, Manuel
AU - Walther, Clemens
N1 - Funding information: Acknowledgment. This work was supported by the Deutsche For-schungsgesellschaft and by the Fonds der Chemischen Industrie. The authors thank S. Zauner for developing the electrolysis procedures.
PY - 2002
Y1 - 2002
N2 - Gas-phase ion chemistry in a Penning trap has been explored for future experiments on the chemical properties of the heaviest elements. The Mainz Cluster Trap, a Penning trap experiment devoted to metal cluster research, has served as a model apparatus for SHIPTRAP which is being installed behind the velocity filter SHIP (Separator for Heavy Ion reaction Products) at the Gesellschaft für Schwerionenforschung (GSI) at Darmstadt. The reactions of stored Ru+ and Os+ with oxygen have been studied and the reaction products MO+ and MO2+ (M = Ru, Os) have been observed. The corresponding rate constants have been measured and the results are discussed with respect to future studies of similar ion-molecule reactions of the element 108 (hassium) in SHIPTRAP.
AB - Gas-phase ion chemistry in a Penning trap has been explored for future experiments on the chemical properties of the heaviest elements. The Mainz Cluster Trap, a Penning trap experiment devoted to metal cluster research, has served as a model apparatus for SHIPTRAP which is being installed behind the velocity filter SHIP (Separator for Heavy Ion reaction Products) at the Gesellschaft für Schwerionenforschung (GSI) at Darmstadt. The reactions of stored Ru+ and Os+ with oxygen have been studied and the reaction products MO+ and MO2+ (M = Ru, Os) have been observed. The corresponding rate constants have been measured and the results are discussed with respect to future studies of similar ion-molecule reactions of the element 108 (hassium) in SHIPTRAP.
KW - Chemistry of superheavy elements
KW - Ion-molecule reactions
KW - Penning trap
KW - Rul, Os, Ti, Zr
UR - http://www.scopus.com/inward/record.url?scp=0036420633&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0036420633
VL - 90
SP - 337
EP - 343
JO - Radiochimica Acta
JF - Radiochimica Acta
SN - 0033-8230
IS - 6
ER -