Investigations on the Nature of Biomineralized Silica by X-Ray Absorption Spectroscopy and Sorption Measurements

Research output: Chapter in book/report/conference proceedingContribution to book/anthologyResearchpeer review

Authors

  • Peter Behrens
  • Gallus Schechner
  • Michael Fröba
  • Bernd Pillep
  • Joe Wong

Research Organisations

External Research Organisations

  • Universität Hamburg
  • Lawrence Livermore National Laboratory
  • Ludwig-Maximilians-Universität München (LMU)
View graph of relations

Details

Original languageEnglish
Title of host publicationOrganosilicon Chemistry Set
Subtitle of host publicationFrom Molecules to Materials
PublisherWiley-Blackwell
Pages17-21
Number of pages5
ISBN (electronic)9783527620777
ISBN (print)9783527323470
Publication statusPublished - 26 Jul 2005

Abstract

Biomineralized silicas are generally described as amorphous gel-like or opaline-type varieties of hydrated SiO2. Our X-ray absorption spectroscopic investigation reveals mid-range order in one of these materials (rice husk silicas) at a length scale of 4-10 Å. The degree of ordering depends on the method used to extract the silica from the samples. This is clearly shown by the investigation of three differently treated rice husk silicas. As confirmed by N2 sorption experiments, these commercially interesting materials exhibit high specific surface areas and broad pore size distributions.

Keywords

    BET isotherme, Biomineralization, Rice husks, Silica, XANES

ASJC Scopus subject areas

Cite this

Investigations on the Nature of Biomineralized Silica by X-Ray Absorption Spectroscopy and Sorption Measurements. / Behrens, Peter; Schechner, Gallus; Fröba, Michael et al.
Organosilicon Chemistry Set: From Molecules to Materials. Wiley-Blackwell, 2005. p. 17-21.

Research output: Chapter in book/report/conference proceedingContribution to book/anthologyResearchpeer review

Behrens, P, Schechner, G, Fröba, M, Pillep, B & Wong, J 2005, Investigations on the Nature of Biomineralized Silica by X-Ray Absorption Spectroscopy and Sorption Measurements. in Organosilicon Chemistry Set: From Molecules to Materials. Wiley-Blackwell, pp. 17-21. https://doi.org/10.1002/9783527620777.ch3c
Behrens, P., Schechner, G., Fröba, M., Pillep, B., & Wong, J. (2005). Investigations on the Nature of Biomineralized Silica by X-Ray Absorption Spectroscopy and Sorption Measurements. In Organosilicon Chemistry Set: From Molecules to Materials (pp. 17-21). Wiley-Blackwell. https://doi.org/10.1002/9783527620777.ch3c
Behrens P, Schechner G, Fröba M, Pillep B, Wong J. Investigations on the Nature of Biomineralized Silica by X-Ray Absorption Spectroscopy and Sorption Measurements. In Organosilicon Chemistry Set: From Molecules to Materials. Wiley-Blackwell. 2005. p. 17-21 doi: 10.1002/9783527620777.ch3c
Behrens, Peter ; Schechner, Gallus ; Fröba, Michael et al. / Investigations on the Nature of Biomineralized Silica by X-Ray Absorption Spectroscopy and Sorption Measurements. Organosilicon Chemistry Set: From Molecules to Materials. Wiley-Blackwell, 2005. pp. 17-21
Download
@inbook{97c2a36de95042a0b9c2fbb93720c899,
title = "Investigations on the Nature of Biomineralized Silica by X-Ray Absorption Spectroscopy and Sorption Measurements",
abstract = "Biomineralized silicas are generally described as amorphous gel-like or opaline-type varieties of hydrated SiO2. Our X-ray absorption spectroscopic investigation reveals mid-range order in one of these materials (rice husk silicas) at a length scale of 4-10 {\AA}. The degree of ordering depends on the method used to extract the silica from the samples. This is clearly shown by the investigation of three differently treated rice husk silicas. As confirmed by N2 sorption experiments, these commercially interesting materials exhibit high specific surface areas and broad pore size distributions.",
keywords = "BET isotherme, Biomineralization, Rice husks, Silica, XANES",
author = "Peter Behrens and Gallus Schechner and Michael Fr{\"o}ba and Bernd Pillep and Joe Wong",
year = "2005",
month = jul,
day = "26",
doi = "10.1002/9783527620777.ch3c",
language = "English",
isbn = "9783527323470",
pages = "17--21",
booktitle = "Organosilicon Chemistry Set",
publisher = "Wiley-Blackwell",
address = "United States",

}

Download

TY - CHAP

T1 - Investigations on the Nature of Biomineralized Silica by X-Ray Absorption Spectroscopy and Sorption Measurements

AU - Behrens, Peter

AU - Schechner, Gallus

AU - Fröba, Michael

AU - Pillep, Bernd

AU - Wong, Joe

PY - 2005/7/26

Y1 - 2005/7/26

N2 - Biomineralized silicas are generally described as amorphous gel-like or opaline-type varieties of hydrated SiO2. Our X-ray absorption spectroscopic investigation reveals mid-range order in one of these materials (rice husk silicas) at a length scale of 4-10 Å. The degree of ordering depends on the method used to extract the silica from the samples. This is clearly shown by the investigation of three differently treated rice husk silicas. As confirmed by N2 sorption experiments, these commercially interesting materials exhibit high specific surface areas and broad pore size distributions.

AB - Biomineralized silicas are generally described as amorphous gel-like or opaline-type varieties of hydrated SiO2. Our X-ray absorption spectroscopic investigation reveals mid-range order in one of these materials (rice husk silicas) at a length scale of 4-10 Å. The degree of ordering depends on the method used to extract the silica from the samples. This is clearly shown by the investigation of three differently treated rice husk silicas. As confirmed by N2 sorption experiments, these commercially interesting materials exhibit high specific surface areas and broad pore size distributions.

KW - BET isotherme

KW - Biomineralization

KW - Rice husks

KW - Silica

KW - XANES

UR - http://www.scopus.com/inward/record.url?scp=84959171172&partnerID=8YFLogxK

U2 - 10.1002/9783527620777.ch3c

DO - 10.1002/9783527620777.ch3c

M3 - Contribution to book/anthology

AN - SCOPUS:84959171172

SN - 9783527323470

SP - 17

EP - 21

BT - Organosilicon Chemistry Set

PB - Wiley-Blackwell

ER -