Details
| Original language | English |
|---|---|
| Pages (from-to) | 129-132 |
| Number of pages | 4 |
| Journal | Hyperfine Interactions |
| Volume | 185 |
| Issue number | 1-3 |
| Publication status | Published - Jul 2008 |
| Externally published | Yes |
Abstract
Systematic 119mSn-Mössbauer spectroscopy studies of three different types of five and six coordinated molybdenum and tungsten stannylidyne complexes are presented. The measured isomer shifts (IS) range from 2.38 to 2.50 mm/s and the quadrupole splittings (QS) from 1.8 to 2.8 mm/s. The values are dependent on the metal centre, the ligand sphere and the charge of the complexes. The influence of the neighbouring metal atoms (Mo, W) and their coordination sphere on the electron density at the tin atom is observed and will be discussed.
Keywords
- Sn-Mössbauer spectroscopy, Molybdenum, Phosphane complexes, Stannylidyne complexes, Tungsten
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Atomic and Molecular Physics, and Optics
- Physics and Astronomy(all)
- Nuclear and High Energy Physics
- Physics and Astronomy(all)
- Condensed Matter Physics
- Chemistry(all)
- Physical and Theoretical Chemistry
Cite this
- Standard
- Harvard
- Apa
- Vancouver
- BibTeX
- RIS
In: Hyperfine Interactions, Vol. 185, No. 1-3, 07.2008, p. 129-132.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Investigation of Mo- and W-stannylidyne complexes by Mössbauer spectroscopy
AU - Rohde, H.
AU - Menzel, M.
AU - Renz, F.
AU - Filippou, A. C.
PY - 2008/7
Y1 - 2008/7
N2 - Systematic 119mSn-Mössbauer spectroscopy studies of three different types of five and six coordinated molybdenum and tungsten stannylidyne complexes are presented. The measured isomer shifts (IS) range from 2.38 to 2.50 mm/s and the quadrupole splittings (QS) from 1.8 to 2.8 mm/s. The values are dependent on the metal centre, the ligand sphere and the charge of the complexes. The influence of the neighbouring metal atoms (Mo, W) and their coordination sphere on the electron density at the tin atom is observed and will be discussed.
AB - Systematic 119mSn-Mössbauer spectroscopy studies of three different types of five and six coordinated molybdenum and tungsten stannylidyne complexes are presented. The measured isomer shifts (IS) range from 2.38 to 2.50 mm/s and the quadrupole splittings (QS) from 1.8 to 2.8 mm/s. The values are dependent on the metal centre, the ligand sphere and the charge of the complexes. The influence of the neighbouring metal atoms (Mo, W) and their coordination sphere on the electron density at the tin atom is observed and will be discussed.
KW - Sn-Mössbauer spectroscopy
KW - Molybdenum
KW - Phosphane complexes
KW - Stannylidyne complexes
KW - Tungsten
UR - http://www.scopus.com/inward/record.url?scp=67650422254&partnerID=8YFLogxK
U2 - 10.1007/s10751-008-9821-7
DO - 10.1007/s10751-008-9821-7
M3 - Article
AN - SCOPUS:67650422254
VL - 185
SP - 129
EP - 132
JO - Hyperfine Interactions
JF - Hyperfine Interactions
SN - 0304-3843
IS - 1-3
ER -