Internal pressure as a key thermodynamic factor to obtain high-temperature superelasticity of shape memory alloys

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  • Kyiv National Taras Shevchenko University
  • Institute of Magnetism
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Original languageEnglish
Pages (from-to)252-254
Number of pages3
JournalMaterials letters
Volume210
Publication statusPublished - 8 Sept 2017

Abstract

Stress–strain loops illustrating the superelastic behaviour of shape memory alloys (SMAs) were computed based on the theory of ferroelastic phase transitions. The predictions of the theory demonstrate the possibility of drastic changes in the stress–strain dependences due to the expansion of the SMA upon heating. Specifically, the computations were carried out taking into account the characteristics of Co-Ni-Ga alloys, which exhibit a high-temperature superelasticity. It is shown that the expansion of crystal lattice, which can be caused by the appearance of small particles and crystal defects, or change of chemical order in SMA, can induce (i) an extension of the temperature range of superelastic behaviour of SMA to high temperatures; (ii) an increase of the superelastic strain at elevated temperatures; (iii) an increase of the stress needed to reach the superelastic strain plateau and (iv) a widening of the hysteresis of stress-induced martensitic transformation. Theoretical results are in a qualitative agreement with experimental data obtained for Co-Ni-Ga alloys.

Keywords

    Defects, Hysteresis, Phase transformation, Shape memory materials, Strain, Stress

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Internal pressure as a key thermodynamic factor to obtain high-temperature superelasticity of shape memory alloys. / Gerstein, Gregory; L'vov, Victor A.; Kosogor, Anna et al.
In: Materials letters, Vol. 210, 08.09.2017, p. 252-254.

Research output: Contribution to journalArticleResearchpeer review

Gerstein G, L'vov VA, Kosogor A, Maier HJ. Internal pressure as a key thermodynamic factor to obtain high-temperature superelasticity of shape memory alloys. Materials letters. 2017 Sept 8;210:252-254. doi: 10.1016/j.matlet.2017.09.034
Gerstein, Gregory ; L'vov, Victor A. ; Kosogor, Anna et al. / Internal pressure as a key thermodynamic factor to obtain high-temperature superelasticity of shape memory alloys. In: Materials letters. 2017 ; Vol. 210. pp. 252-254.
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abstract = "Stress–strain loops illustrating the superelastic behaviour of shape memory alloys (SMAs) were computed based on the theory of ferroelastic phase transitions. The predictions of the theory demonstrate the possibility of drastic changes in the stress–strain dependences due to the expansion of the SMA upon heating. Specifically, the computations were carried out taking into account the characteristics of Co-Ni-Ga alloys, which exhibit a high-temperature superelasticity. It is shown that the expansion of crystal lattice, which can be caused by the appearance of small particles and crystal defects, or change of chemical order in SMA, can induce (i) an extension of the temperature range of superelastic behaviour of SMA to high temperatures; (ii) an increase of the superelastic strain at elevated temperatures; (iii) an increase of the stress needed to reach the superelastic strain plateau and (iv) a widening of the hysteresis of stress-induced martensitic transformation. Theoretical results are in a qualitative agreement with experimental data obtained for Co-Ni-Ga alloys.",
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AU - Gerstein, Gregory

AU - L'vov, Victor A.

AU - Kosogor, Anna

AU - Maier, Hans J.

N1 - Funding information: Financial support by the Deutsche Forschungsgemeinschaft (DFG) under grant MA1175/44-1 is gratefully acknowledged. The authors thank Prof. Chumlyakov for providing the single crystals.

PY - 2017/9/8

Y1 - 2017/9/8

N2 - Stress–strain loops illustrating the superelastic behaviour of shape memory alloys (SMAs) were computed based on the theory of ferroelastic phase transitions. The predictions of the theory demonstrate the possibility of drastic changes in the stress–strain dependences due to the expansion of the SMA upon heating. Specifically, the computations were carried out taking into account the characteristics of Co-Ni-Ga alloys, which exhibit a high-temperature superelasticity. It is shown that the expansion of crystal lattice, which can be caused by the appearance of small particles and crystal defects, or change of chemical order in SMA, can induce (i) an extension of the temperature range of superelastic behaviour of SMA to high temperatures; (ii) an increase of the superelastic strain at elevated temperatures; (iii) an increase of the stress needed to reach the superelastic strain plateau and (iv) a widening of the hysteresis of stress-induced martensitic transformation. Theoretical results are in a qualitative agreement with experimental data obtained for Co-Ni-Ga alloys.

AB - Stress–strain loops illustrating the superelastic behaviour of shape memory alloys (SMAs) were computed based on the theory of ferroelastic phase transitions. The predictions of the theory demonstrate the possibility of drastic changes in the stress–strain dependences due to the expansion of the SMA upon heating. Specifically, the computations were carried out taking into account the characteristics of Co-Ni-Ga alloys, which exhibit a high-temperature superelasticity. It is shown that the expansion of crystal lattice, which can be caused by the appearance of small particles and crystal defects, or change of chemical order in SMA, can induce (i) an extension of the temperature range of superelastic behaviour of SMA to high temperatures; (ii) an increase of the superelastic strain at elevated temperatures; (iii) an increase of the stress needed to reach the superelastic strain plateau and (iv) a widening of the hysteresis of stress-induced martensitic transformation. Theoretical results are in a qualitative agreement with experimental data obtained for Co-Ni-Ga alloys.

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KW - Hysteresis

KW - Phase transformation

KW - Shape memory materials

KW - Strain

KW - Stress

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