Details
| Original language | English |
|---|---|
| Pages (from-to) | 168-173 |
| Number of pages | 6 |
| Journal | Journal of molecular spectroscopy |
| Volume | 152 |
| Issue number | 1 |
| Publication status | Published - Mar 1992 |
Abstract
We present an extended concept to describe the interdependence among the parameters of a multivariate fit. Based on Femenias' "freedom" parameters, our concept provides the "overall dependence" of a parameter and its distribution among the "pair dependences" of this parameter from two or more other parameters. Finally, we propose a "freedom-cofreedom" matrix, displaying the parameter interdependence in multiplicative manner. Its computation can easily be implemented in the usual routines for spectroscopic fitting purposes.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Atomic and Molecular Physics, and Optics
- Chemistry(all)
- Spectroscopy
- Chemistry(all)
- Physical and Theoretical Chemistry
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In: Journal of molecular spectroscopy, Vol. 152, No. 1, 03.1992, p. 168-173.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Interdependence of parameters in multivariate fits
AU - Grabow, J. U.
AU - Heineking, N.
AU - Stahl, W.
PY - 1992/3
Y1 - 1992/3
N2 - We present an extended concept to describe the interdependence among the parameters of a multivariate fit. Based on Femenias' "freedom" parameters, our concept provides the "overall dependence" of a parameter and its distribution among the "pair dependences" of this parameter from two or more other parameters. Finally, we propose a "freedom-cofreedom" matrix, displaying the parameter interdependence in multiplicative manner. Its computation can easily be implemented in the usual routines for spectroscopic fitting purposes.
AB - We present an extended concept to describe the interdependence among the parameters of a multivariate fit. Based on Femenias' "freedom" parameters, our concept provides the "overall dependence" of a parameter and its distribution among the "pair dependences" of this parameter from two or more other parameters. Finally, we propose a "freedom-cofreedom" matrix, displaying the parameter interdependence in multiplicative manner. Its computation can easily be implemented in the usual routines for spectroscopic fitting purposes.
UR - http://www.scopus.com/inward/record.url?scp=0000223801&partnerID=8YFLogxK
U2 - 10.1016/0022-2852(92)90126-9
DO - 10.1016/0022-2852(92)90126-9
M3 - Article
AN - SCOPUS:0000223801
VL - 152
SP - 168
EP - 173
JO - Journal of molecular spectroscopy
JF - Journal of molecular spectroscopy
SN - 0022-2852
IS - 1
ER -