Integration of low dimensional crystalline Si into functional epitaxial oxides

Research output: Contribution to journalArticleResearchpeer review

Authors

  • Apurba Laha
  • E. Bugiel
  • R. Dargis
  • D. Schwendt
  • M. Badylevich
  • V. V. Afanas'ev
  • A. Stesmans
  • A. Fissel
  • H. J. Osten

External Research Organisations

  • KU Leuven
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Details

Original languageEnglish
Pages (from-to)633-637
Number of pages5
JournalMicroelectronics journal
Volume40
Issue number3
Early online date25 Jul 2008
Publication statusPublished - Mar 2009

Abstract

In this work we show that by efficiently exploiting the growth kinetics during molecular beam epitaxy (MBE) one could create Si nanostructures of different dimensions. Examples are Si quantum dots (QD) or quantum wells (QW), which are buried into an epitaxial rare-earth oxide, e.g. Gd2O3. Electrical measurements carried out on Pt/Gd2O3/Si MOS capacitors comprised with Si-QD demonstrate that such well embedded Si-QD with average size of 5 nm and density of 2×1012 cm-2 exhibit very good charge storage capacity with suitable retention (∼105 s) and endurance (∼105 write/erase cycles) characteristics. The Pt/Gd2O3/Si (metal-oxide-semiconductor (MOS)) basic memory cells with embedded Si-QD display large programming window (∼1.5-2 V) and fast writing speed and hence could be a potential candidate for future non-volatile memory application. The optical absorption of such Si-QD embedded into epitaxial Gd2O3 was found to exhibit a spectral threshold maximum up to 2.9±0.1 eV depending on their sizes, inferring a significant influence of quantum confinement on the QD/oxide interface band diagram. Ultra-thin single-crystalline Si-QW with epitaxial insulator (Gd2O3) as the barrier layers were grown by a novel approach based on cooperative vapor phase MBE on Si wafer with sharp interfaces between well and barriers. The current-voltage characteristics obtained for such structure exhibits negative differential resistance at lower temperature, making them a good candidate for resonant tunneling devices.

Keywords

    Epitaxial gadolinium oxide, Nonvolatile memories, Oxide-semiconductor-oxide quantum well, Resonant tunneling diode, Si quantum dots

ASJC Scopus subject areas

Cite this

Integration of low dimensional crystalline Si into functional epitaxial oxides. / Laha, Apurba; Bugiel, E.; Dargis, R. et al.
In: Microelectronics journal, Vol. 40, No. 3, 03.2009, p. 633-637.

Research output: Contribution to journalArticleResearchpeer review

Laha, A, Bugiel, E, Dargis, R, Schwendt, D, Badylevich, M, Afanas'ev, VV, Stesmans, A, Fissel, A & Osten, HJ 2009, 'Integration of low dimensional crystalline Si into functional epitaxial oxides', Microelectronics journal, vol. 40, no. 3, pp. 633-637. https://doi.org/10.1016/j.mejo.2008.06.064
Laha, A., Bugiel, E., Dargis, R., Schwendt, D., Badylevich, M., Afanas'ev, V. V., Stesmans, A., Fissel, A., & Osten, H. J. (2009). Integration of low dimensional crystalline Si into functional epitaxial oxides. Microelectronics journal, 40(3), 633-637. https://doi.org/10.1016/j.mejo.2008.06.064
Laha A, Bugiel E, Dargis R, Schwendt D, Badylevich M, Afanas'ev VV et al. Integration of low dimensional crystalline Si into functional epitaxial oxides. Microelectronics journal. 2009 Mar;40(3):633-637. Epub 2008 Jul 25. doi: 10.1016/j.mejo.2008.06.064
Laha, Apurba ; Bugiel, E. ; Dargis, R. et al. / Integration of low dimensional crystalline Si into functional epitaxial oxides. In: Microelectronics journal. 2009 ; Vol. 40, No. 3. pp. 633-637.
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abstract = "In this work we show that by efficiently exploiting the growth kinetics during molecular beam epitaxy (MBE) one could create Si nanostructures of different dimensions. Examples are Si quantum dots (QD) or quantum wells (QW), which are buried into an epitaxial rare-earth oxide, e.g. Gd2O3. Electrical measurements carried out on Pt/Gd2O3/Si MOS capacitors comprised with Si-QD demonstrate that such well embedded Si-QD with average size of 5 nm and density of 2×1012 cm-2 exhibit very good charge storage capacity with suitable retention (∼105 s) and endurance (∼105 write/erase cycles) characteristics. The Pt/Gd2O3/Si (metal-oxide-semiconductor (MOS)) basic memory cells with embedded Si-QD display large programming window (∼1.5-2 V) and fast writing speed and hence could be a potential candidate for future non-volatile memory application. The optical absorption of such Si-QD embedded into epitaxial Gd2O3 was found to exhibit a spectral threshold maximum up to 2.9±0.1 eV depending on their sizes, inferring a significant influence of quantum confinement on the QD/oxide interface band diagram. Ultra-thin single-crystalline Si-QW with epitaxial insulator (Gd2O3) as the barrier layers were grown by a novel approach based on cooperative vapor phase MBE on Si wafer with sharp interfaces between well and barriers. The current-voltage characteristics obtained for such structure exhibits negative differential resistance at lower temperature, making them a good candidate for resonant tunneling devices.",
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T1 - Integration of low dimensional crystalline Si into functional epitaxial oxides

AU - Laha, Apurba

AU - Bugiel, E.

AU - Dargis, R.

AU - Schwendt, D.

AU - Badylevich, M.

AU - Afanas'ev, V. V.

AU - Stesmans, A.

AU - Fissel, A.

AU - Osten, H. J.

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N2 - In this work we show that by efficiently exploiting the growth kinetics during molecular beam epitaxy (MBE) one could create Si nanostructures of different dimensions. Examples are Si quantum dots (QD) or quantum wells (QW), which are buried into an epitaxial rare-earth oxide, e.g. Gd2O3. Electrical measurements carried out on Pt/Gd2O3/Si MOS capacitors comprised with Si-QD demonstrate that such well embedded Si-QD with average size of 5 nm and density of 2×1012 cm-2 exhibit very good charge storage capacity with suitable retention (∼105 s) and endurance (∼105 write/erase cycles) characteristics. The Pt/Gd2O3/Si (metal-oxide-semiconductor (MOS)) basic memory cells with embedded Si-QD display large programming window (∼1.5-2 V) and fast writing speed and hence could be a potential candidate for future non-volatile memory application. The optical absorption of such Si-QD embedded into epitaxial Gd2O3 was found to exhibit a spectral threshold maximum up to 2.9±0.1 eV depending on their sizes, inferring a significant influence of quantum confinement on the QD/oxide interface band diagram. Ultra-thin single-crystalline Si-QW with epitaxial insulator (Gd2O3) as the barrier layers were grown by a novel approach based on cooperative vapor phase MBE on Si wafer with sharp interfaces between well and barriers. The current-voltage characteristics obtained for such structure exhibits negative differential resistance at lower temperature, making them a good candidate for resonant tunneling devices.

AB - In this work we show that by efficiently exploiting the growth kinetics during molecular beam epitaxy (MBE) one could create Si nanostructures of different dimensions. Examples are Si quantum dots (QD) or quantum wells (QW), which are buried into an epitaxial rare-earth oxide, e.g. Gd2O3. Electrical measurements carried out on Pt/Gd2O3/Si MOS capacitors comprised with Si-QD demonstrate that such well embedded Si-QD with average size of 5 nm and density of 2×1012 cm-2 exhibit very good charge storage capacity with suitable retention (∼105 s) and endurance (∼105 write/erase cycles) characteristics. The Pt/Gd2O3/Si (metal-oxide-semiconductor (MOS)) basic memory cells with embedded Si-QD display large programming window (∼1.5-2 V) and fast writing speed and hence could be a potential candidate for future non-volatile memory application. The optical absorption of such Si-QD embedded into epitaxial Gd2O3 was found to exhibit a spectral threshold maximum up to 2.9±0.1 eV depending on their sizes, inferring a significant influence of quantum confinement on the QD/oxide interface band diagram. Ultra-thin single-crystalline Si-QW with epitaxial insulator (Gd2O3) as the barrier layers were grown by a novel approach based on cooperative vapor phase MBE on Si wafer with sharp interfaces between well and barriers. The current-voltage characteristics obtained for such structure exhibits negative differential resistance at lower temperature, making them a good candidate for resonant tunneling devices.

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KW - Nonvolatile memories

KW - Oxide-semiconductor-oxide quantum well

KW - Resonant tunneling diode

KW - Si quantum dots

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JF - Microelectronics journal

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