Implementation of spin crossover compounds into electrospun nanofibers

Research output: Contribution to journalArticleResearchpeer review

Authors

  • B. Dreyer
  • Dominik Natke
  • Stephan Klimke
  • S. Baskas
  • Ralf Sindelar
  • G. Klingelhöfer
  • Franz Renz

Research Organisations

External Research Organisations

  • Johannes Gutenberg University Mainz
  • University of Applied Sciences and Arts Hannover (HsH)
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Details

Original languageEnglish
Article number8
JournalHyperfine Interactions
Volume239
Issue number1
Early online date2 Jan 2018
Publication statusPublished - 1 Dec 2018

Abstract

We synthesised a series of Iron(II)-triazole compounds and used the electrospinning procedure to incorporate spin crossover compounds (SCO) into polylactic acid polymer fibers. Composite fiber/SCO compounds of [Fe(NH2-trz)3](BF4)2 as well as [Fe(Htrz)2(trz)]BF4 were investigated via Mössbauer spectroscopy at 293 K and 77 K. The Mössbauer studies show that the spin crossover behavior is maintained in the polymer matrix.

Keywords

    Electrospinning, Iron complexes, Mössbauer, SCO, Triazole

ASJC Scopus subject areas

Cite this

Implementation of spin crossover compounds into electrospun nanofibers. / Dreyer, B.; Natke, Dominik; Klimke, Stephan et al.
In: Hyperfine Interactions, Vol. 239, No. 1, 8, 01.12.2018.

Research output: Contribution to journalArticleResearchpeer review

Dreyer, B, Natke, D, Klimke, S, Baskas, S, Sindelar, R, Klingelhöfer, G & Renz, F 2018, 'Implementation of spin crossover compounds into electrospun nanofibers', Hyperfine Interactions, vol. 239, no. 1, 8. https://doi.org/10.1007/s10751-017-1483-x
Dreyer, B., Natke, D., Klimke, S., Baskas, S., Sindelar, R., Klingelhöfer, G., & Renz, F. (2018). Implementation of spin crossover compounds into electrospun nanofibers. Hyperfine Interactions, 239(1), Article 8. https://doi.org/10.1007/s10751-017-1483-x
Dreyer B, Natke D, Klimke S, Baskas S, Sindelar R, Klingelhöfer G et al. Implementation of spin crossover compounds into electrospun nanofibers. Hyperfine Interactions. 2018 Dec 1;239(1):8. Epub 2018 Jan 2. doi: 10.1007/s10751-017-1483-x
Dreyer, B. ; Natke, Dominik ; Klimke, Stephan et al. / Implementation of spin crossover compounds into electrospun nanofibers. In: Hyperfine Interactions. 2018 ; Vol. 239, No. 1.
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AU - Dreyer, B.

AU - Natke, Dominik

AU - Klimke, Stephan

AU - Baskas, S.

AU - Sindelar, Ralf

AU - Klingelhöfer, G.

AU - Renz, Franz

N1 - Funding information: The authors would like to thank the Hochschule Hannover (HsH), Leibniz Universität Hannover (LUH) and the Laboratory of Nano and Quantum Engineering (LNQE) for financial support.

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AB - We synthesised a series of Iron(II)-triazole compounds and used the electrospinning procedure to incorporate spin crossover compounds (SCO) into polylactic acid polymer fibers. Composite fiber/SCO compounds of [Fe(NH2-trz)3](BF4)2 as well as [Fe(Htrz)2(trz)]BF4 were investigated via Mössbauer spectroscopy at 293 K and 77 K. The Mössbauer studies show that the spin crossover behavior is maintained in the polymer matrix.

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