Details
Original language | English |
---|---|
Article number | 8 |
Journal | Hyperfine Interactions |
Volume | 239 |
Issue number | 1 |
Early online date | 2 Jan 2018 |
Publication status | Published - 1 Dec 2018 |
Abstract
We synthesised a series of Iron(II)-triazole compounds and used the electrospinning procedure to incorporate spin crossover compounds (SCO) into polylactic acid polymer fibers. Composite fiber/SCO compounds of [Fe(NH2-trz)3](BF4)2 as well as [Fe(Htrz)2(trz)]BF4 were investigated via Mössbauer spectroscopy at 293 K and 77 K. The Mössbauer studies show that the spin crossover behavior is maintained in the polymer matrix.
Keywords
- Electrospinning, Iron complexes, Mössbauer, SCO, Triazole
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Atomic and Molecular Physics, and Optics
- Physics and Astronomy(all)
- Nuclear and High Energy Physics
- Physics and Astronomy(all)
- Condensed Matter Physics
- Chemistry(all)
- Physical and Theoretical Chemistry
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In: Hyperfine Interactions, Vol. 239, No. 1, 8, 01.12.2018.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Implementation of spin crossover compounds into electrospun nanofibers
AU - Dreyer, B.
AU - Natke, Dominik
AU - Klimke, Stephan
AU - Baskas, S.
AU - Sindelar, Ralf
AU - Klingelhöfer, G.
AU - Renz, Franz
N1 - Funding information: The authors would like to thank the Hochschule Hannover (HsH), Leibniz Universität Hannover (LUH) and the Laboratory of Nano and Quantum Engineering (LNQE) for financial support.
PY - 2018/12/1
Y1 - 2018/12/1
N2 - We synthesised a series of Iron(II)-triazole compounds and used the electrospinning procedure to incorporate spin crossover compounds (SCO) into polylactic acid polymer fibers. Composite fiber/SCO compounds of [Fe(NH2-trz)3](BF4)2 as well as [Fe(Htrz)2(trz)]BF4 were investigated via Mössbauer spectroscopy at 293 K and 77 K. The Mössbauer studies show that the spin crossover behavior is maintained in the polymer matrix.
AB - We synthesised a series of Iron(II)-triazole compounds and used the electrospinning procedure to incorporate spin crossover compounds (SCO) into polylactic acid polymer fibers. Composite fiber/SCO compounds of [Fe(NH2-trz)3](BF4)2 as well as [Fe(Htrz)2(trz)]BF4 were investigated via Mössbauer spectroscopy at 293 K and 77 K. The Mössbauer studies show that the spin crossover behavior is maintained in the polymer matrix.
KW - Electrospinning
KW - Iron complexes
KW - Mössbauer
KW - SCO
KW - Triazole
UR - http://www.scopus.com/inward/record.url?scp=85040022468&partnerID=8YFLogxK
U2 - 10.1007/s10751-017-1483-x
DO - 10.1007/s10751-017-1483-x
M3 - Article
AN - SCOPUS:85040022468
VL - 239
JO - Hyperfine Interactions
JF - Hyperfine Interactions
SN - 0304-3843
IS - 1
M1 - 8
ER -