Details
| Original language | English |
|---|---|
| Pages (from-to) | 188-190 |
| Number of pages | 3 |
| Journal | Inorganic chemistry communications |
| Volume | 2 |
| Issue number | 5 |
| Publication status | Published - 1 May 1999 |
Abstract
The condensation product of 2-pyridinecarboxaldehyde N-oxide with triethylenetetramine exists in solution in the contracted form with two outer imidazolidine rings. In the copper and zinc complexes, three ligand isomers, containing none (L1), one (L2) or two (L3) imidazolidine rings, occur as proved by the X-ray structure analysis of [ZnL1](ClO4)2, [CuL2](ClO4)2 and [ZnL3(DMSO)2](ClO4)2.
Keywords
- Copper(II) complexes, Imidazolidine complexes, Ligand isomers, Zinc(II) complexes
ASJC Scopus subject areas
- Chemistry(all)
- Physical and Theoretical Chemistry
- Chemistry(all)
- Inorganic Chemistry
- Materials Science(all)
- Materials Chemistry
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In: Inorganic chemistry communications, Vol. 2, No. 5, 01.05.1999, p. 188-190.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Imidazolidine ring-formation/cleavage due to intracomplex coordinative activation
AU - Boča, Miroslav
AU - Baran, Peter
AU - Boča, Roman
AU - Kickelbick, Guido
AU - Renz, Franz
AU - Linert, Wolfgang
PY - 1999/5/1
Y1 - 1999/5/1
N2 - The condensation product of 2-pyridinecarboxaldehyde N-oxide with triethylenetetramine exists in solution in the contracted form with two outer imidazolidine rings. In the copper and zinc complexes, three ligand isomers, containing none (L1), one (L2) or two (L3) imidazolidine rings, occur as proved by the X-ray structure analysis of [ZnL1](ClO4)2, [CuL2](ClO4)2 and [ZnL3(DMSO)2](ClO4)2.
AB - The condensation product of 2-pyridinecarboxaldehyde N-oxide with triethylenetetramine exists in solution in the contracted form with two outer imidazolidine rings. In the copper and zinc complexes, three ligand isomers, containing none (L1), one (L2) or two (L3) imidazolidine rings, occur as proved by the X-ray structure analysis of [ZnL1](ClO4)2, [CuL2](ClO4)2 and [ZnL3(DMSO)2](ClO4)2.
KW - Copper(II) complexes
KW - Imidazolidine complexes
KW - Ligand isomers
KW - Zinc(II) complexes
UR - http://www.scopus.com/inward/record.url?scp=0033467629&partnerID=8YFLogxK
U2 - 10.1016/S1387-7003(99)00044-1
DO - 10.1016/S1387-7003(99)00044-1
M3 - Article
AN - SCOPUS:0033467629
VL - 2
SP - 188
EP - 190
JO - Inorganic chemistry communications
JF - Inorganic chemistry communications
SN - 1387-7003
IS - 5
ER -