High-spin Schiff-base dinuclear iron(III) complexes bridged by N-oxide ligands

Research output: Contribution to journal › Article › Research › peer review

Authors

  • Ivan Nemec
  • Roman Boča
  • Milan Gembický
  • Lubor Dlháň
  • Radovan Herchel
  • Franz Renz

Research Organisations

External Research Organisations

  • Slovak University of Technology in Bratislava
  • SUNY Buffalo
  • Palacky University
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Details

Original languageEnglish
Pages (from-to)4754-4759
Number of pages6
JournalInorganica chimica acta
Volume362
Issue number13
Publication statusPublished - 15 Oct 2009

Abstract

Synthesis and structure of dinuclear complexes [{FeIII(L5)}b{FeIII(L5)}](BPh4)2, where L5 is a pentadentate Schiff-base ligand, b is a bidentate N-oxide bridging ligand based on bipyridine, is reported. Magnetic behavior is investigated in terms of the magnetic susceptibility, magnetization, and Mössbauer spectroscopy revealing that the complexes are high-spin over the whole temperature region.

Keywords

    Iron(III) complex, Magnetism, Mössbauer spectroscopy, N-oxide ligands, Schiff-base ligands, Structure

ASJC Scopus subject areas

Cite this

High-spin Schiff-base dinuclear iron(III) complexes bridged by N-oxide ligands. / Nemec, Ivan; Boča, Roman; Gembický, Milan et al.
In: Inorganica chimica acta, Vol. 362, No. 13, 15.10.2009, p. 4754-4759.

Research output: Contribution to journal › Article › Research › peer review

Nemec, I, Boča, R, Gembický, M, Dlháň, L, Herchel, R & Renz, F 2009, 'High-spin Schiff-base dinuclear iron(III) complexes bridged by N-oxide ligands', Inorganica chimica acta, vol. 362, no. 13, pp. 4754-4759. https://doi.org/10.1016/j.ica.2009.06.057
Nemec, I., Boča, R., Gembický, M., Dlháň, L., Herchel, R., & Renz, F. (2009). High-spin Schiff-base dinuclear iron(III) complexes bridged by N-oxide ligands. Inorganica chimica acta, 362(13), 4754-4759. https://doi.org/10.1016/j.ica.2009.06.057
Nemec I, Boča R, Gembický M, Dlháň L, Herchel R, Renz F. High-spin Schiff-base dinuclear iron(III) complexes bridged by N-oxide ligands. Inorganica chimica acta. 2009 Oct 15;362(13):4754-4759. doi: 10.1016/j.ica.2009.06.057
Nemec, Ivan ; Boča, Roman ; Gembický, Milan et al. / High-spin Schiff-base dinuclear iron(III) complexes bridged by N-oxide ligands. In: Inorganica chimica acta. 2009 ; Vol. 362, No. 13. pp. 4754-4759.
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abstract = "Synthesis and structure of dinuclear complexes [{FeIII(L5)}b{FeIII(L5)}](BPh4)2, where L5 is a pentadentate Schiff-base ligand, b is a bidentate N-oxide bridging ligand based on bipyridine, is reported. Magnetic behavior is investigated in terms of the magnetic susceptibility, magnetization, and M{\"o}ssbauer spectroscopy revealing that the complexes are high-spin over the whole temperature region.",
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AU - Nemec, Ivan

AU - Boča, Roman

AU - Gembický, Milan

AU - Dlháň, Lubor

AU - Herchel, Radovan

AU - Renz, Franz

N1 - Funding Information: The authors would like to acknowledge Prof. Philip Coppens for providing diffractometer measurement time and to Prof. Jozef Kožíšek for preliminary X-ray experiments. Grant agencies and project sponsors (Slovakia: VEGA 1/0213/08, APVV 0006-07, COST-0006-06, VVCE-0004-07; Czech Republic: MSM6198959218, KAN115600801; USA: NSF CHE 0236317(PC); Germany: Leibniz University (ZFM)) are acknowledged for the financial support.

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KW - Magnetism

KW - Mössbauer spectroscopy

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