Details
| Original language | English |
|---|---|
| Pages (from-to) | 57-66 |
| Number of pages | 10 |
| Journal | Arkivoc |
| Volume | 2004 |
| Issue number | 13 |
| Publication status | Published - 24 Sept 2004 |
Abstract
Tetracarbonyl(norbornadiene)chromium(0) was used as complexation reagent in the synthesis of tetracarbonylchromium chelate complexes of dppe, dppb, dppf, DIOP, BINAP, and Tol-BINAP. In all cases the reactions took place under mild reaction conditions with excellent, almost quantitative yields. X-ray crystal structure analyses of the dppf and BINAP tetracarbonylchromium(0) complexes are presented.
Keywords
- BINAP, Chromium complexes, DIOP, dppb, dppe, dppf, Norbornadiene, Tol-binap
ASJC Scopus subject areas
- Chemistry(all)
- Organic Chemistry
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In: Arkivoc, Vol. 2004, No. 13, 24.09.2004, p. 57-66.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - High yield synthesis and structures of some achiral and chiral (diphosphine)tetracarbonylchromium(0) chelate complexes with tetracarbonyl(norbornadiene)chromium(0) as complexation reagent
AU - Strotmann, Markus
AU - Wartchow, Rudolf
AU - Butenschön, Holger
PY - 2004/9/24
Y1 - 2004/9/24
N2 - Tetracarbonyl(norbornadiene)chromium(0) was used as complexation reagent in the synthesis of tetracarbonylchromium chelate complexes of dppe, dppb, dppf, DIOP, BINAP, and Tol-BINAP. In all cases the reactions took place under mild reaction conditions with excellent, almost quantitative yields. X-ray crystal structure analyses of the dppf and BINAP tetracarbonylchromium(0) complexes are presented.
AB - Tetracarbonyl(norbornadiene)chromium(0) was used as complexation reagent in the synthesis of tetracarbonylchromium chelate complexes of dppe, dppb, dppf, DIOP, BINAP, and Tol-BINAP. In all cases the reactions took place under mild reaction conditions with excellent, almost quantitative yields. X-ray crystal structure analyses of the dppf and BINAP tetracarbonylchromium(0) complexes are presented.
KW - BINAP
KW - Chromium complexes
KW - DIOP
KW - dppb
KW - dppe
KW - dppf
KW - Norbornadiene
KW - Tol-binap
UR - http://www.scopus.com/inward/record.url?scp=5444260578&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:5444260578
VL - 2004
SP - 57
EP - 66
JO - Arkivoc
JF - Arkivoc
SN - 1424-6376
IS - 13
ER -