High Power Factor vs. High zT: A review of Thermoelectric Materials for High-Temperature Application

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Original languageEnglish
Article number1058
Pages (from-to)1058
Number of pages32
JournalEntropy
Volume21
Issue number11
Publication statusPublished - 29 Oct 2019

Abstract

Energy harvesting with thermoelectric materials has been investigated with increasing attention over recent decades. However, the vast number of various material classes makes it difficult to maintain an overview of the best candidates. Thus, we revitalize Ioffe plots as a useful tool for making the thermoelectric properties of a material obvious and easily comparable. These plots enable us to consider not only the efficiency of the material by the figure of merit zT but also the power factor and entropy conductivity as separate parameters. This is especially important for high-temperature applications, where a critical look at the impact of the power factor and thermal conductivity is mandatory. Thus, this review focuses on material classes for high-temperature applications and emphasizes the best candidates within the material classes of oxides, oxyselenides, Zintl phases, half-Heusler compounds, and SiGe alloys. An overall comparison between these material classes with respect to either a high efficiency or a high power output is discussed.

Keywords

    Energy harvesting, Energy materials, Thermoelectric materials

ASJC Scopus subject areas

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High Power Factor vs. High zT: A review of Thermoelectric Materials for High-Temperature Application. / Wolf, Mario; Hinterding, Richard; Feldhoff, Armin.
In: Entropy, Vol. 21, No. 11, 1058, 29.10.2019, p. 1058.

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abstract = "Energy harvesting with thermoelectric materials has been investigated with increasing attention over recent decades. However, the vast number of various material classes makes it difficult to maintain an overview of the best candidates. Thus, we revitalize Ioffe plots as a useful tool for making the thermoelectric properties of a material obvious and easily comparable. These plots enable us to consider not only the efficiency of the material by the figure of merit zT but also the power factor and entropy conductivity as separate parameters. This is especially important for high-temperature applications, where a critical look at the impact of the power factor and thermal conductivity is mandatory. Thus, this review focuses on material classes for high-temperature applications and emphasizes the best candidates within the material classes of oxides, oxyselenides, Zintl phases, half-Heusler compounds, and SiGe alloys. An overall comparison between these material classes with respect to either a high efficiency or a high power output is discussed.",
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AU - Wolf, Mario

AU - Hinterding, Richard

AU - Feldhoff, Armin

N1 - Funding Information: This work was funded by the Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)-project number 325156807. The publication of this article was funded by the Open Access fund of Leibniz University Hannover.

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N2 - Energy harvesting with thermoelectric materials has been investigated with increasing attention over recent decades. However, the vast number of various material classes makes it difficult to maintain an overview of the best candidates. Thus, we revitalize Ioffe plots as a useful tool for making the thermoelectric properties of a material obvious and easily comparable. These plots enable us to consider not only the efficiency of the material by the figure of merit zT but also the power factor and entropy conductivity as separate parameters. This is especially important for high-temperature applications, where a critical look at the impact of the power factor and thermal conductivity is mandatory. Thus, this review focuses on material classes for high-temperature applications and emphasizes the best candidates within the material classes of oxides, oxyselenides, Zintl phases, half-Heusler compounds, and SiGe alloys. An overall comparison between these material classes with respect to either a high efficiency or a high power output is discussed.

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