Details
| Original language | English |
|---|---|
| Pages (from-to) | 63-67 |
| Number of pages | 5 |
| Journal | Hyperfine Interactions |
| Volume | 205 |
| Issue number | 1-3 |
| Early online date | 11 Nov 2011 |
| Publication status | Published - Mar 2012 |
Abstract
The nonanuclear coordination compound [Mo IV{(CN)Fe III(3-methyl-saldptn)} 8]Cl 4 exhibits multiple spin transitions (3-methyl-saldptn = N,N′-bis(3′′-methyl-2′′-hydroxy-benzyliden)-1,7-diamino-4-azaheptane). This spin crossover cluster is bound via a self-assembled monolayer onto a two dimensional array gold surface. Mössbauer spectroscopy indicates that the thermally and optically induced spin crossover of the compound is maintained. Thereby, the foundation for its potential practical application (e. g. in the field of information storage) was laid.
Keywords
- Au surface, Mössbauer spectroscopy, Nonanuclear, Self-assembled monolayer, Spin crossover
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Atomic and Molecular Physics, and Optics
- Physics and Astronomy(all)
- Nuclear and High Energy Physics
- Physics and Astronomy(all)
- Condensed Matter Physics
- Chemistry(all)
- Physical and Theoretical Chemistry
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In: Hyperfine Interactions, Vol. 205, No. 1-3, 03.2012, p. 63-67.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Gold-surface binding of molecular switches studied by Mössbauer spectroscopy
AU - Homenya, Patrick
AU - Messerschmidt, Markus
AU - Martinez, Victor
AU - Cheng, Yajun
AU - Gutmann, Jochen S.
AU - Klein, Michael
AU - Jung, Stefan
AU - Wolff, Morris
AU - Saadat, Reza
AU - Nariaki, Driss
AU - Boča, Roman
AU - Klingelhöfer, Göstar
AU - Tremel, Wolfgang
AU - Renz, Franz
AU - Tahir, Muhammad
N1 - Funding Information: Acknowledgements Grant Agencies (Slovakia: VEGA 1/0052/11, VVCE 0004-07; Germany: Leibniz University, LNQE, ZFM; Uni Mainz, MWFZ; DAAD; DFG Re-1627; EU: Structural Funds, Interreg IIIA) are acknowledged for the financial support.
PY - 2012/3
Y1 - 2012/3
N2 - The nonanuclear coordination compound [Mo IV{(CN)Fe III(3-methyl-saldptn)} 8]Cl 4 exhibits multiple spin transitions (3-methyl-saldptn = N,N′-bis(3′′-methyl-2′′-hydroxy-benzyliden)-1,7-diamino-4-azaheptane). This spin crossover cluster is bound via a self-assembled monolayer onto a two dimensional array gold surface. Mössbauer spectroscopy indicates that the thermally and optically induced spin crossover of the compound is maintained. Thereby, the foundation for its potential practical application (e. g. in the field of information storage) was laid.
AB - The nonanuclear coordination compound [Mo IV{(CN)Fe III(3-methyl-saldptn)} 8]Cl 4 exhibits multiple spin transitions (3-methyl-saldptn = N,N′-bis(3′′-methyl-2′′-hydroxy-benzyliden)-1,7-diamino-4-azaheptane). This spin crossover cluster is bound via a self-assembled monolayer onto a two dimensional array gold surface. Mössbauer spectroscopy indicates that the thermally and optically induced spin crossover of the compound is maintained. Thereby, the foundation for its potential practical application (e. g. in the field of information storage) was laid.
KW - Au surface
KW - Mössbauer spectroscopy
KW - Nonanuclear
KW - Self-assembled monolayer
KW - Spin crossover
UR - http://www.scopus.com/inward/record.url?scp=84859584744&partnerID=8YFLogxK
U2 - 10.1007/s10751-011-0426-1
DO - 10.1007/s10751-011-0426-1
M3 - Article
AN - SCOPUS:84859584744
VL - 205
SP - 63
EP - 67
JO - Hyperfine Interactions
JF - Hyperfine Interactions
SN - 0304-3843
IS - 1-3
ER -