Gel permeation chromatography of water-soluble organic matter with deionized water as eluent II. Spectroscopic and chemical characterization of fractions obtained from an aqueous litter extract

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Original languageEnglish
Pages (from-to)447-457
Number of pages11
JournalScience of the Total Environment, The
Volume81-82
Issue numberC
Publication statusPublished - Jun 1989
Externally publishedYes

Abstract

Water-soluble organic matter extracted from a mull litter horizon under ash and alder was fractionated on Fractogel TSK. With a single fractionation step six fractions could be obtained. The fractions were studied by IR and solution-state 13C NMR spectroscopy as well as by methanolysis. According to 13C NMR spectroscopy, carbohydrates are the dominant constituents of the bulk sample. Alkyl-carbon components are of minor importante and there is only little evidence of aromatic compounds. Data from gas chromatography of methanolysis products shows that sugar acids, sugar alcohols, and cyclitols considerably contribute to the carbohydrate proportion of some of the fractions.

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Gel permeation chromatography of water-soluble organic matter with deionized water as eluent II. Spectroscopic and chemical characterization of fractions obtained from an aqueous litter extract. / Guggenberger, G.; Kögel-Knabner, I.; Haumaier, L. et al.
In: Science of the Total Environment, The, Vol. 81-82, No. C, 06.1989, p. 447-457.

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abstract = "Water-soluble organic matter extracted from a mull litter horizon under ash and alder was fractionated on Fractogel TSK. With a single fractionation step six fractions could be obtained. The fractions were studied by IR and solution-state 13C NMR spectroscopy as well as by methanolysis. According to 13C NMR spectroscopy, carbohydrates are the dominant constituents of the bulk sample. Alkyl-carbon components are of minor importante and there is only little evidence of aromatic compounds. Data from gas chromatography of methanolysis products shows that sugar acids, sugar alcohols, and cyclitols considerably contribute to the carbohydrate proportion of some of the fractions.",
author = "G. Guggenberger and I. K{\"o}gel-Knabner and L. Haumaier and W. Zech",
note = "Funding information: We acknowledgefi nancial support from the Deutsche Forschungsgemeinschaft (SFB 137). We also are indebtedt o Mr. K. Ishiwada (Kontron) for obtainingt he 13C NMR spectra, to Mr. M. GHiBner for gas chromatography-massps ectrometry measurementasn, d to Dr. M. Perdue for critical comments.",
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TY - JOUR

T1 - Gel permeation chromatography of water-soluble organic matter with deionized water as eluent II. Spectroscopic and chemical characterization of fractions obtained from an aqueous litter extract

AU - Guggenberger, G.

AU - Kögel-Knabner, I.

AU - Haumaier, L.

AU - Zech, W.

N1 - Funding information: We acknowledgefi nancial support from the Deutsche Forschungsgemeinschaft (SFB 137). We also are indebtedt o Mr. K. Ishiwada (Kontron) for obtainingt he 13C NMR spectra, to Mr. M. GHiBner for gas chromatography-massps ectrometry measurementasn, d to Dr. M. Perdue for critical comments.

PY - 1989/6

Y1 - 1989/6

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U2 - 10.1016/0048-9697(89)90153-8

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VL - 81-82

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