Details
| Original language | English |
|---|---|
| Title of host publication | Organosilicon Chemistry Set |
| Subtitle of host publication | From Molecules to Materials |
| Publisher | Wiley-Blackwell |
| Pages | 649-669 |
| Number of pages | 21 |
| ISBN (electronic) | 9783527620777 |
| ISBN (print) | 9783527323470 |
| Publication status | Published - 26 Jul 2005 |
| Externally published | Yes |
Abstract
Organometallic complexes like cobalticinium cations act as structuredirecting agents in the synthesis of microporous solids with open frameworks composed of silica. During the hydrothermal synthesis they become occluded by the crystallizing framework. In contrast to the post-synthetic methods that have been used before to prepare organometallic/silica composites, this direct synthesis gives homogeneous, stoichiometric and highly crystalline compounds. In the nanostructured materials, the occluded complexes are spatially organized, and often they are aligned. Also, they are stabilized and protected by the surrounding framework. Organometallic/silica composites prepared by direct synthesis in which the complex acts as structure-directing agent thus offer the possibility to combine the advantages of solid-state and molecular materials.
Keywords
- Materials, Microporous Solids, Organometallic complexes, Porosils, Structure-directed Synthesis
ASJC Scopus subject areas
- Chemistry(all)
- General Chemistry
Cite this
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Organosilicon Chemistry Set: From Molecules to Materials. Wiley-Blackwell, 2005. p. 649-669.
Research output: Chapter in book/report/conference proceeding › Contribution to book/anthology › Research › peer review
}
TY - CHAP
T1 - Functionalized Structure-Directing Agents for the Direct Synthesis of Nanostructured Materials
AU - Behrens, Peter
PY - 2005/7/26
Y1 - 2005/7/26
N2 - Organometallic complexes like cobalticinium cations act as structuredirecting agents in the synthesis of microporous solids with open frameworks composed of silica. During the hydrothermal synthesis they become occluded by the crystallizing framework. In contrast to the post-synthetic methods that have been used before to prepare organometallic/silica composites, this direct synthesis gives homogeneous, stoichiometric and highly crystalline compounds. In the nanostructured materials, the occluded complexes are spatially organized, and often they are aligned. Also, they are stabilized and protected by the surrounding framework. Organometallic/silica composites prepared by direct synthesis in which the complex acts as structure-directing agent thus offer the possibility to combine the advantages of solid-state and molecular materials.
AB - Organometallic complexes like cobalticinium cations act as structuredirecting agents in the synthesis of microporous solids with open frameworks composed of silica. During the hydrothermal synthesis they become occluded by the crystallizing framework. In contrast to the post-synthetic methods that have been used before to prepare organometallic/silica composites, this direct synthesis gives homogeneous, stoichiometric and highly crystalline compounds. In the nanostructured materials, the occluded complexes are spatially organized, and often they are aligned. Also, they are stabilized and protected by the surrounding framework. Organometallic/silica composites prepared by direct synthesis in which the complex acts as structure-directing agent thus offer the possibility to combine the advantages of solid-state and molecular materials.
KW - Materials
KW - Microporous Solids
KW - Organometallic complexes
KW - Porosils
KW - Structure-directed Synthesis
UR - http://www.scopus.com/inward/record.url?scp=84959093517&partnerID=8YFLogxK
U2 - 10.1002/9783527620777.ch103b
DO - 10.1002/9783527620777.ch103b
M3 - Contribution to book/anthology
AN - SCOPUS:84959093517
SN - 9783527323470
SP - 649
EP - 669
BT - Organosilicon Chemistry Set
PB - Wiley-Blackwell
ER -