Formation of a sulphur-sulphur bridged radical cation during the oxidation of 1,4-dithian by hydroxyl radicals

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Authors

  • Detlef Bahnemann
  • Klaus Dieter Asmus

External Research Organisations

  • Helmholtz-Zentrum Berlin für Materialien und Energie (HZB)
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Details

Original languageEnglish
Pages (from-to)238-239
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number7
Publication statusPublished - 1975
Externally publishedYes

Abstract

A transient radical cation with a three-electron bond between the two sulphur atoms in the 1,4-positions is formed upon oxidation of 1,4-dithian by OH radicals in aqueous solutions at low solute concentration.

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Formation of a sulphur-sulphur bridged radical cation during the oxidation of 1,4-dithian by hydroxyl radicals. / Bahnemann, Detlef; Asmus, Klaus Dieter.
In: Journal of the Chemical Society, Chemical Communications, No. 7, 1975, p. 238-239.

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abstract = "A transient radical cation with a three-electron bond between the two sulphur atoms in the 1,4-positions is formed upon oxidation of 1,4-dithian by OH radicals in aqueous solutions at low solute concentration.",
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PY - 1975

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