Details
| Original language | English |
|---|---|
| Pages (from-to) | 21-30 |
| Number of pages | 10 |
| Journal | Chemical physics |
| Volume | 277 |
| Issue number | 1 |
| Publication status | Published - 1 Mar 2002 |
| Externally published | Yes |
Abstract
Temperature dependent fluorescence, excitation and absorption spectra of two spin crossover Fe(II) complexes with 2,6-bis(benzimidazole-2′-yl)pyridine, Febz-H2 (containing 2(ClO4-) as counter ions) and Febz-H (uncharged), have been observed. The origin of the unexpected observed fluorescence is discussed. Polarized absorption spectra in stretched polymer films are described and aid to the interpretation as well as extended PPP-MO calculations. The observed fluorescence spectra are not only the assignment of electronic transitions but also shown to be useful for the extraction of high-spin (HS) and low-spin (LS) contents in temperature dependent spin crossover systems.
Keywords
- Fluorescence spectra, Iron(II) complexes, MO calculation, Polarized electronic absorption spectra, Spin crossover
ASJC Scopus subject areas
- Physics and Astronomy(all)
- General Physics and Astronomy
- Chemistry(all)
- Physical and Theoretical Chemistry
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In: Chemical physics, Vol. 277, No. 1, 01.03.2002, p. 21-30.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Fluorescence spectra of Fe(II) spin crossover complexes with 2,6-bis(benzimidazole-2′-yl)pyridine
AU - Hasegawa, Miki
AU - Renz, Franz
AU - Hara, Takeshi
AU - Kikuchi, Yuko
AU - Fukuda, Yutaka
AU - Okubo, Jun
AU - Hoshi, Toshihiko
AU - Linert, Wolfgang
N1 - Funding Information: Thanks for financial support are due to the “Fonds zur Förderung der Wissenschaftlichen Forschung in Österreich” (Project 15048-CHE) to the Training and Mobility of Researchers Network (TMR) project “Thermal and Optical Spin State Switching” (TOSS) supported by the European Community under the Contract number ERB-FMRX-CT98-0199, to the European Science Foundation under the project “Molecular Magnets” and Science Fund of Japan Private School Promotion Foundation.
PY - 2002/3/1
Y1 - 2002/3/1
N2 - Temperature dependent fluorescence, excitation and absorption spectra of two spin crossover Fe(II) complexes with 2,6-bis(benzimidazole-2′-yl)pyridine, Febz-H2 (containing 2(ClO4-) as counter ions) and Febz-H (uncharged), have been observed. The origin of the unexpected observed fluorescence is discussed. Polarized absorption spectra in stretched polymer films are described and aid to the interpretation as well as extended PPP-MO calculations. The observed fluorescence spectra are not only the assignment of electronic transitions but also shown to be useful for the extraction of high-spin (HS) and low-spin (LS) contents in temperature dependent spin crossover systems.
AB - Temperature dependent fluorescence, excitation and absorption spectra of two spin crossover Fe(II) complexes with 2,6-bis(benzimidazole-2′-yl)pyridine, Febz-H2 (containing 2(ClO4-) as counter ions) and Febz-H (uncharged), have been observed. The origin of the unexpected observed fluorescence is discussed. Polarized absorption spectra in stretched polymer films are described and aid to the interpretation as well as extended PPP-MO calculations. The observed fluorescence spectra are not only the assignment of electronic transitions but also shown to be useful for the extraction of high-spin (HS) and low-spin (LS) contents in temperature dependent spin crossover systems.
KW - Fluorescence spectra
KW - Iron(II) complexes
KW - MO calculation
KW - Polarized electronic absorption spectra
KW - Spin crossover
UR - http://www.scopus.com/inward/record.url?scp=0036499015&partnerID=8YFLogxK
U2 - 10.1016/S0301-0104(01)00706-6
DO - 10.1016/S0301-0104(01)00706-6
M3 - Article
AN - SCOPUS:0036499015
VL - 277
SP - 21
EP - 30
JO - Chemical physics
JF - Chemical physics
SN - 0301-0104
IS - 1
ER -