Features of Multistage Thermoelastic B2–R–B19′ Martensitic Transformations in Heterophase Single Crystals of Ti–Ni Alloys

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Original languageEnglish
Pages (from-to)1116-1125
Number of pages10
JournalRussian physics journal
Volume57
Issue number8
Publication statusPublished - 4 Dec 2014

Abstract

In heterophase Ti50.0–xNi50.0+x (х = 0.8–1.0 at.%) single crystals after aging at 823 K for 1.5 h at the heating/cooling rate (15 ± 1) K/min and stepwise aging at 823 K for 1.5 h plus aging at 573–623 K for 1 h, multi-stage martensitic transformations are observed: there are three peaks of heat release in the DSC (differential scanning calorimetry) curves. The first peak is associated with a B2–R-transformation and increased electrical resistance ρ and the other two correspond to the development of an R–B19′-martensitic transformation occurring in two stages, and are followed by a two-stage drop of electrical resistance in the ρ(T) plot. The high-temperature stage of the R–B19′-martensitic transition is associated with transformations under the action of local stress fields in the vicinity of disperse Ti3Ni4 particles measuring ~400 nm, while the low-temperature stage is associated with transformations in the spaces between large particles containing fine disperse β′-phase particles isostructural with respect to the matrix, measuring 3–5 nm, which are formed during slow cooling from 823 K or in the course of low-temperature aging at 573–623 K.

Keywords

    disperse particles, single crystals, thermoelastic martensitic transformations

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Features of Multistage Thermoelastic B2–R–B19′ Martensitic Transformations in Heterophase Single Crystals of Ti–Ni Alloys. / Panchenko, E. Yu; Chumlyakov, Yu I.; Maier, H.
In: Russian physics journal, Vol. 57, No. 8, 04.12.2014, p. 1116-1125.

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title = "Features of Multistage Thermoelastic B2–R–B19′ Martensitic Transformations in Heterophase Single Crystals of Ti–Ni Alloys",
abstract = "In heterophase Ti50.0–xNi50.0+x (х = 0.8–1.0 at.%) single crystals after aging at 823 K for 1.5 h at the heating/cooling rate (15 ± 1) K/min and stepwise aging at 823 K for 1.5 h plus aging at 573–623 K for 1 h, multi-stage martensitic transformations are observed: there are three peaks of heat release in the DSC (differential scanning calorimetry) curves. The first peak is associated with a B2–R-transformation and increased electrical resistance ρ and the other two correspond to the development of an R–B19′-martensitic transformation occurring in two stages, and are followed by a two-stage drop of electrical resistance in the ρ(T) plot. The high-temperature stage of the R–B19′-martensitic transition is associated with transformations under the action of local stress fields in the vicinity of disperse Ti3Ni4 particles measuring ~400 nm, while the low-temperature stage is associated with transformations in the spaces between large particles containing fine disperse β′-phase particles isostructural with respect to the matrix, measuring 3–5 nm, which are formed during slow cooling from 823 K or in the course of low-temperature aging at 573–623 K.",
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author = "Panchenko, {E. Yu} and Chumlyakov, {Yu I.} and H. Maier",
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T1 - Features of Multistage Thermoelastic B2–R–B19′ Martensitic Transformations in Heterophase Single Crystals of Ti–Ni Alloys

AU - Panchenko, E. Yu

AU - Chumlyakov, Yu I.

AU - Maier, H.

N1 - Publisher Copyright: © 2014, Springer Science+Business Media New York. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2014/12/4

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N2 - In heterophase Ti50.0–xNi50.0+x (х = 0.8–1.0 at.%) single crystals after aging at 823 K for 1.5 h at the heating/cooling rate (15 ± 1) K/min and stepwise aging at 823 K for 1.5 h plus aging at 573–623 K for 1 h, multi-stage martensitic transformations are observed: there are three peaks of heat release in the DSC (differential scanning calorimetry) curves. The first peak is associated with a B2–R-transformation and increased electrical resistance ρ and the other two correspond to the development of an R–B19′-martensitic transformation occurring in two stages, and are followed by a two-stage drop of electrical resistance in the ρ(T) plot. The high-temperature stage of the R–B19′-martensitic transition is associated with transformations under the action of local stress fields in the vicinity of disperse Ti3Ni4 particles measuring ~400 nm, while the low-temperature stage is associated with transformations in the spaces between large particles containing fine disperse β′-phase particles isostructural with respect to the matrix, measuring 3–5 nm, which are formed during slow cooling from 823 K or in the course of low-temperature aging at 573–623 K.

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