Details
| Original language | English |
|---|---|
| Pages (from-to) | 128-135 |
| Number of pages | 8 |
| Journal | Catalysis today |
| Volume | 118 |
| Issue number | 1-2 |
| Publication status | Published - 30 Oct 2006 |
Abstract
Perovskite hollow fibre membranes of the composition BaCoxFeyZr1-x-yO3-δ (BCFZ) were prepared by a spinning process and subsequent sintering. The fibres were successfully tested in the production of pure oxygen and oxygen-enriched air as well as in a catalytic membrane reactor for the partial oxidation of methane to synthesis gas. In addition to BCFZ, for comparison perovskites of the composition Ba0.5Sr0.5Co0.8Fe0.2O3- δ (BSCF) and Ba0.5Sr0.5Zn0.2Fe0.8O3- δ (BSZF) as well as SrCo0.8Fe0.2O3-δ (SCF) were prepared and tested. The atomic structure of the grain boundaries and their influence on oxygen transport are discussed. The thermal expansion coefficient is derived from in situ high temperature XRD.
Keywords
- Disk geometry, Hollow fibre, Oxygen separator
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Chemistry(all)
- General Chemistry
Cite this
- Standard
- Harvard
- Apa
- Vancouver
- BibTeX
- RIS
In: Catalysis today, Vol. 118, No. 1-2, 30.10.2006, p. 128-135.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Evaluation of perovskites in hollow fibre and disk geometry in catalytic membrane reactors and in oxygen separators
AU - Caro, J.
AU - Wang, H. H.
AU - Tablet, C.
AU - Kleinert, A.
AU - Feldhoff, A.
AU - Schiestel, T.
AU - Kilgus, M.
AU - Kölsch, P.
AU - Werth, S.
N1 - Funding Information: The authors thank the German Federal Ministry of Education and Research for the financial support of the project CaMeRa (Catalytic Membrane Reactor) under the auspices of ConNeCat (Competence Network Catalysis). H. Wang thanks the Humboldt Foundation for financial support.
PY - 2006/10/30
Y1 - 2006/10/30
N2 - Perovskite hollow fibre membranes of the composition BaCoxFeyZr1-x-yO3-δ (BCFZ) were prepared by a spinning process and subsequent sintering. The fibres were successfully tested in the production of pure oxygen and oxygen-enriched air as well as in a catalytic membrane reactor for the partial oxidation of methane to synthesis gas. In addition to BCFZ, for comparison perovskites of the composition Ba0.5Sr0.5Co0.8Fe0.2O3- δ (BSCF) and Ba0.5Sr0.5Zn0.2Fe0.8O3- δ (BSZF) as well as SrCo0.8Fe0.2O3-δ (SCF) were prepared and tested. The atomic structure of the grain boundaries and their influence on oxygen transport are discussed. The thermal expansion coefficient is derived from in situ high temperature XRD.
AB - Perovskite hollow fibre membranes of the composition BaCoxFeyZr1-x-yO3-δ (BCFZ) were prepared by a spinning process and subsequent sintering. The fibres were successfully tested in the production of pure oxygen and oxygen-enriched air as well as in a catalytic membrane reactor for the partial oxidation of methane to synthesis gas. In addition to BCFZ, for comparison perovskites of the composition Ba0.5Sr0.5Co0.8Fe0.2O3- δ (BSCF) and Ba0.5Sr0.5Zn0.2Fe0.8O3- δ (BSZF) as well as SrCo0.8Fe0.2O3-δ (SCF) were prepared and tested. The atomic structure of the grain boundaries and their influence on oxygen transport are discussed. The thermal expansion coefficient is derived from in situ high temperature XRD.
KW - Disk geometry
KW - Hollow fibre
KW - Oxygen separator
UR - http://www.scopus.com/inward/record.url?scp=33748955621&partnerID=8YFLogxK
U2 - 10.1016/j.cattod.2005.12.015
DO - 10.1016/j.cattod.2005.12.015
M3 - Article
AN - SCOPUS:33748955621
VL - 118
SP - 128
EP - 135
JO - Catalysis today
JF - Catalysis today
SN - 0920-5861
IS - 1-2
ER -