Details
| Original language | English |
|---|---|
| Pages (from-to) | 8592-8600 |
| Number of pages | 9 |
| Journal | LANGMUIR |
| Volume | 29 |
| Issue number | 27 |
| Early online date | 26 Jun 2013 |
| Publication status | Published - 9 Jul 2013 |
Abstract
Two types of metal-organic frameworks (MOFs) have been synthesized and evaluated in the separation of C2 and C3 olefins and paraffins. Whereas Co2(dhtp) (=Co-CPO-27 = Co-MOF-74) and Mg 2(dhtp) show an adsorption selectivity for the olefins ethene and propene over the paraffins ethane and propane, the zeolitic imidazolate framework ZIF-8 behaves in the opposite way and preferentially adsorbs the alkane. Consequently, in breakthrough experiments, the olefins or paraffins, respectively, can be separated.
ASJC Scopus subject areas
- Materials Science(all)
- General Materials Science
- Physics and Astronomy(all)
- Condensed Matter Physics
- Physics and Astronomy(all)
- Surfaces and Interfaces
- Chemistry(all)
- Spectroscopy
- Chemistry(all)
- Electrochemistry
Cite this
- Standard
- Harvard
- Apa
- Vancouver
- BibTeX
- RIS
In: LANGMUIR, Vol. 29, No. 27, 09.07.2013, p. 8592-8600.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Ethene/ethane and propene/propane separation via the olefin and paraffin selective metal-organic framework adsorbents CPO-27 and ZIF-8
AU - Böhme, Ulrike
AU - Barth, Benjamin
AU - Paula, Carolin
AU - Kuhnt, Andreas
AU - Schwieger, Wilhelm
AU - Mundstock, Alexander
AU - Caro, Jürgen
AU - Hartmann, Martin
PY - 2013/7/9
Y1 - 2013/7/9
N2 - Two types of metal-organic frameworks (MOFs) have been synthesized and evaluated in the separation of C2 and C3 olefins and paraffins. Whereas Co2(dhtp) (=Co-CPO-27 = Co-MOF-74) and Mg 2(dhtp) show an adsorption selectivity for the olefins ethene and propene over the paraffins ethane and propane, the zeolitic imidazolate framework ZIF-8 behaves in the opposite way and preferentially adsorbs the alkane. Consequently, in breakthrough experiments, the olefins or paraffins, respectively, can be separated.
AB - Two types of metal-organic frameworks (MOFs) have been synthesized and evaluated in the separation of C2 and C3 olefins and paraffins. Whereas Co2(dhtp) (=Co-CPO-27 = Co-MOF-74) and Mg 2(dhtp) show an adsorption selectivity for the olefins ethene and propene over the paraffins ethane and propane, the zeolitic imidazolate framework ZIF-8 behaves in the opposite way and preferentially adsorbs the alkane. Consequently, in breakthrough experiments, the olefins or paraffins, respectively, can be separated.
UR - http://www.scopus.com/inward/record.url?scp=84880179341&partnerID=8YFLogxK
U2 - 10.1021/la401471g
DO - 10.1021/la401471g
M3 - Article
C2 - 23802617
AN - SCOPUS:84880179341
VL - 29
SP - 8592
EP - 8600
JO - LANGMUIR
JF - LANGMUIR
SN - 0743-7463
IS - 27
ER -