Effect of Solvents on Thermomechanical Properties and Piezoelectric Beta-phase of PVDF-TrFE Films

Research output: Chapter in book/report/conference proceedingConference contributionResearchpeer review

Authors

  • Antonia Isabel Kuhn
  • Oleksandr Gryshkov
  • Birgit Glasmacher

Research Organisations

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Details

Original languageEnglish
Title of host publicationProceedings of the 2020 IEEE International Conference on Electrical Engineering and Photonics, EExPolytech 2020
EditorsElena Velichko
PublisherInstitute of Electrical and Electronics Engineers Inc.
Pages204-207
Number of pages4
ISBN (electronic)9781728188782
ISBN (print)978-1-7281-8879-9
Publication statusPublished - 2020
Event2020 IEEE International Conference on Electrical Engineering and Photonics, EExPolytech 2020 - Saint Petersburg, Russian Federation
Duration: 15 Oct 202016 Oct 2020

Abstract

Co-polymer polyvinylidene fluoride-co-trifluoroethylene (PVDF-TrFE) is a promising piezoelectric material for a range of medical and industrial applications such as tissue engineering, sensors and membrane technics. In this regard, blend electrospinning is an ideal method to produce suitable polymeric nano- and micro-fiber scaffolds or membranes from polymer solutions. Stable electrospinning process is strongly dependent on PVDF-TrFE solution properties. Thus, this study aimed at evaluating the effect of different suitable solvents on physical properties PVDF-TrFE polymer solutions and produced films with different solvent combinations and mixing ratios. The results indicate that solution viscosities range between 5.47 and 37.17 Pa.s. Furthermore, piezoelectric phase fraction and crystallinity of PVDF-TrFE films were characterized using Fourier Transform Infrared Spectroscopy and Differential Scanning Calorimetry, respectively. All films exhibited a piezoelectric polar beta-phase formation. The crystalline beta-phase fraction of the most of the films was higher than the value of the initial material (77%). Results demonstrate the influence of solvent combinations and mixing ratios on melting temperature and crystallinity.

Keywords

    Crystallinity, DSC, FTIR, Piezoelectric phase fraction, PVDF-TrFE, Solvents, Viscosity

ASJC Scopus subject areas

Cite this

Effect of Solvents on Thermomechanical Properties and Piezoelectric Beta-phase of PVDF-TrFE Films. / Kuhn, Antonia Isabel; Gryshkov, Oleksandr; Glasmacher, Birgit.
Proceedings of the 2020 IEEE International Conference on Electrical Engineering and Photonics, EExPolytech 2020. ed. / Elena Velichko. Institute of Electrical and Electronics Engineers Inc., 2020. p. 204-207 9243865.

Research output: Chapter in book/report/conference proceedingConference contributionResearchpeer review

Kuhn, AI, Gryshkov, O & Glasmacher, B 2020, Effect of Solvents on Thermomechanical Properties and Piezoelectric Beta-phase of PVDF-TrFE Films. in E Velichko (ed.), Proceedings of the 2020 IEEE International Conference on Electrical Engineering and Photonics, EExPolytech 2020., 9243865, Institute of Electrical and Electronics Engineers Inc., pp. 204-207, 2020 IEEE International Conference on Electrical Engineering and Photonics, EExPolytech 2020, Saint Petersburg, Russian Federation, 15 Oct 2020. https://doi.org/10.1109/EExPolytech50912.2020.9243865
Kuhn, A. I., Gryshkov, O., & Glasmacher, B. (2020). Effect of Solvents on Thermomechanical Properties and Piezoelectric Beta-phase of PVDF-TrFE Films. In E. Velichko (Ed.), Proceedings of the 2020 IEEE International Conference on Electrical Engineering and Photonics, EExPolytech 2020 (pp. 204-207). Article 9243865 Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/EExPolytech50912.2020.9243865
Kuhn AI, Gryshkov O, Glasmacher B. Effect of Solvents on Thermomechanical Properties and Piezoelectric Beta-phase of PVDF-TrFE Films. In Velichko E, editor, Proceedings of the 2020 IEEE International Conference on Electrical Engineering and Photonics, EExPolytech 2020. Institute of Electrical and Electronics Engineers Inc. 2020. p. 204-207. 9243865 doi: 10.1109/EExPolytech50912.2020.9243865
Kuhn, Antonia Isabel ; Gryshkov, Oleksandr ; Glasmacher, Birgit. / Effect of Solvents on Thermomechanical Properties and Piezoelectric Beta-phase of PVDF-TrFE Films. Proceedings of the 2020 IEEE International Conference on Electrical Engineering and Photonics, EExPolytech 2020. editor / Elena Velichko. Institute of Electrical and Electronics Engineers Inc., 2020. pp. 204-207
Download
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