Effect of oscillating magnetic fields on freezing of a colloidal dispersion of superparamagnetic nanoparticles

Research output: Contribution to journalArticleResearchpeer review

Authors

  • Laura Otero
  • Antonio C. Rodríguez
  • Irene Morales
  • Rocío Costo
  • Patricia de la Presa
  • Pedro D. Sanz

External Research Organisations

  • Spanish National Research Council (CSIC)
  • Complutense University of Madrid (UCM)
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Details

Original languageEnglish
Article number111440
Number of pages8
JournalJournal of food engineering
Volume347
Early online date6 Feb 2023
Publication statusPublished - Jun 2023
Externally publishedYes

Abstract

Several studies suggest that single-domain biogenic magnetic nanoparticles could play a major role on the effectiveness of oscillating magnetic fields (OMFs) in improving food freezing. To evaluate the potential role of superparamagnetic biogenic particles, we performed freezing experiments in a colloidal dispersion of <10-nm maghemite nanoparticles (MNPs) subjected or not to a 31.3-mT OMF at 50 Hz. Our results show that, at our experimental conditions, Néel mechanism governs the alignment of magnetic dipole moments and, therefore, no significant MNPs rotation, able to disturb the ordering of water molecules, should be expected during OMF experiments. Accordingly, no effects of the applied OMF were observed either on supercooling, ice nucleation, or on freezing kinetics even though heat removal was slightly increased during the precooling step. These results suggest that weak OMFs usually applied in commercial freezers should not produce any significant effect on superparamagnetic nanoparticles present in food that could improve the freezing process.

Keywords

    Freezing, Freezing kinetics, Oscillating magnetic fields, Supercooling, Superparamagnetic nanoparticles

ASJC Scopus subject areas

Cite this

Effect of oscillating magnetic fields on freezing of a colloidal dispersion of superparamagnetic nanoparticles. / Otero, Laura; Rodríguez, Antonio C.; Morales, Irene et al.
In: Journal of food engineering, Vol. 347, 111440, 06.2023.

Research output: Contribution to journalArticleResearchpeer review

Otero L, Rodríguez AC, Morales I, Costo R, Presa PDL, Sanz PD. Effect of oscillating magnetic fields on freezing of a colloidal dispersion of superparamagnetic nanoparticles. Journal of food engineering. 2023 Jun;347:111440. Epub 2023 Feb 6. doi: 10.1016/j.jfoodeng.2023.111440
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AU - Otero, Laura

AU - Rodríguez, Antonio C.

AU - Morales, Irene

AU - Costo, Rocío

AU - Presa, Patricia de la

AU - Sanz, Pedro D.

N1 - Publisher Copyright: © 2023 The Authors

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N2 - Several studies suggest that single-domain biogenic magnetic nanoparticles could play a major role on the effectiveness of oscillating magnetic fields (OMFs) in improving food freezing. To evaluate the potential role of superparamagnetic biogenic particles, we performed freezing experiments in a colloidal dispersion of <10-nm maghemite nanoparticles (MNPs) subjected or not to a 31.3-mT OMF at 50 Hz. Our results show that, at our experimental conditions, Néel mechanism governs the alignment of magnetic dipole moments and, therefore, no significant MNPs rotation, able to disturb the ordering of water molecules, should be expected during OMF experiments. Accordingly, no effects of the applied OMF were observed either on supercooling, ice nucleation, or on freezing kinetics even though heat removal was slightly increased during the precooling step. These results suggest that weak OMFs usually applied in commercial freezers should not produce any significant effect on superparamagnetic nanoparticles present in food that could improve the freezing process.

AB - Several studies suggest that single-domain biogenic magnetic nanoparticles could play a major role on the effectiveness of oscillating magnetic fields (OMFs) in improving food freezing. To evaluate the potential role of superparamagnetic biogenic particles, we performed freezing experiments in a colloidal dispersion of <10-nm maghemite nanoparticles (MNPs) subjected or not to a 31.3-mT OMF at 50 Hz. Our results show that, at our experimental conditions, Néel mechanism governs the alignment of magnetic dipole moments and, therefore, no significant MNPs rotation, able to disturb the ordering of water molecules, should be expected during OMF experiments. Accordingly, no effects of the applied OMF were observed either on supercooling, ice nucleation, or on freezing kinetics even though heat removal was slightly increased during the precooling step. These results suggest that weak OMFs usually applied in commercial freezers should not produce any significant effect on superparamagnetic nanoparticles present in food that could improve the freezing process.

KW - Freezing

KW - Freezing kinetics

KW - Oscillating magnetic fields

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