Effect of excess aluminium on phase relations in the system Qz-Ab- Or: experimental investigation at 2kbar and reduced H2O-activity

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Authors

  • Francois Holtz
  • Wilhelm Johannes
  • Michel Pichavant

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  • Centre national de la recherche scientifique (CNRS)
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Original languageEnglish
Pages (from-to)137-152
Number of pages16
JournalEuropean Journal of Mineralogy
Volume4
Issue number1
Publication statusPublished - 31 Jan 1992

Abstract

Liquidus phase relationships have been investigated in the peraluminous system Qz (SiO2) - Ab (NaAlSi3O8) - Or (KAlSi3O8) - Al2O3 - H2O - CO2. The experiments have been performed at 2kbar, 750 to 850°C, and at H2O-undersaturated conditions (H2O-activity close to 0.5). An aluminosilicate phase (mullite) coexists with all melts of peraluminous compositions. The comparison of the subaluminous and the peraluminous systems shows that all liquidus temperatures are lower in the peraluminous system. The position of the quartz-feldspar cotectic is slightly shifted towards more Qz-rich compositions in the peraluminous system. The projected composition of the thermal minimum is Qz35Ab36 Or29 in the subaluminous system and Qz38Ab34Or28 in the peraluminous system. Peraluminous melts coexisting with mullite contain 1.2 to 2.4% normative corundum at the investigated temperatures (750 to 850°C). Different temperatures have not been observed for the beginning of melting of crystal mixtures composed of quartz + alkali feldspar and quartz + alkali feldspar + sillimanite. This may be due to kinetic problems and is discussed. -from Authors

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Effect of excess aluminium on phase relations in the system Qz-Ab- Or: experimental investigation at 2kbar and reduced H2O-activity. / Holtz, Francois; Johannes, Wilhelm; Pichavant, Michel.
In: European Journal of Mineralogy, Vol. 4, No. 1, 31.01.1992, p. 137-152.

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abstract = "Liquidus phase relationships have been investigated in the peraluminous system Qz (SiO2) - Ab (NaAlSi3O8) - Or (KAlSi3O8) - Al2O3 - H2O - CO2. The experiments have been performed at 2kbar, 750 to 850°C, and at H2O-undersaturated conditions (H2O-activity close to 0.5). An aluminosilicate phase (mullite) coexists with all melts of peraluminous compositions. The comparison of the subaluminous and the peraluminous systems shows that all liquidus temperatures are lower in the peraluminous system. The position of the quartz-feldspar cotectic is slightly shifted towards more Qz-rich compositions in the peraluminous system. The projected composition of the thermal minimum is Qz35Ab36 Or29 in the subaluminous system and Qz38Ab34Or28 in the peraluminous system. Peraluminous melts coexisting with mullite contain 1.2 to 2.4% normative corundum at the investigated temperatures (750 to 850°C). Different temperatures have not been observed for the beginning of melting of crystal mixtures composed of quartz + alkali feldspar and quartz + alkali feldspar + sillimanite. This may be due to kinetic problems and is discussed. -from Authors",
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AU - Holtz, Francois

AU - Johannes, Wilhelm

AU - Pichavant, Michel

N1 - Copyright: Copyright 2018 Elsevier B.V., All rights reserved.

PY - 1992/1/31

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N2 - Liquidus phase relationships have been investigated in the peraluminous system Qz (SiO2) - Ab (NaAlSi3O8) - Or (KAlSi3O8) - Al2O3 - H2O - CO2. The experiments have been performed at 2kbar, 750 to 850°C, and at H2O-undersaturated conditions (H2O-activity close to 0.5). An aluminosilicate phase (mullite) coexists with all melts of peraluminous compositions. The comparison of the subaluminous and the peraluminous systems shows that all liquidus temperatures are lower in the peraluminous system. The position of the quartz-feldspar cotectic is slightly shifted towards more Qz-rich compositions in the peraluminous system. The projected composition of the thermal minimum is Qz35Ab36 Or29 in the subaluminous system and Qz38Ab34Or28 in the peraluminous system. Peraluminous melts coexisting with mullite contain 1.2 to 2.4% normative corundum at the investigated temperatures (750 to 850°C). Different temperatures have not been observed for the beginning of melting of crystal mixtures composed of quartz + alkali feldspar and quartz + alkali feldspar + sillimanite. This may be due to kinetic problems and is discussed. -from Authors

AB - Liquidus phase relationships have been investigated in the peraluminous system Qz (SiO2) - Ab (NaAlSi3O8) - Or (KAlSi3O8) - Al2O3 - H2O - CO2. The experiments have been performed at 2kbar, 750 to 850°C, and at H2O-undersaturated conditions (H2O-activity close to 0.5). An aluminosilicate phase (mullite) coexists with all melts of peraluminous compositions. The comparison of the subaluminous and the peraluminous systems shows that all liquidus temperatures are lower in the peraluminous system. The position of the quartz-feldspar cotectic is slightly shifted towards more Qz-rich compositions in the peraluminous system. The projected composition of the thermal minimum is Qz35Ab36 Or29 in the subaluminous system and Qz38Ab34Or28 in the peraluminous system. Peraluminous melts coexisting with mullite contain 1.2 to 2.4% normative corundum at the investigated temperatures (750 to 850°C). Different temperatures have not been observed for the beginning of melting of crystal mixtures composed of quartz + alkali feldspar and quartz + alkali feldspar + sillimanite. This may be due to kinetic problems and is discussed. -from Authors

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