Details
| Original language | English |
|---|---|
| Pages (from-to) | 901-905 |
| Number of pages | 5 |
| Journal | Beilstein Journal of Organic Chemistry |
| Volume | 15 |
| Early online date | 12 Apr 2019 |
| Publication status | Published - 2019 |
| Externally published | Yes |
Abstract
An efficient one-pot synthesis for Janus-type fullerenol derivatives and how to characterize them is reported. This synthesis provides access to asymmetrically substituted fullerenol with five substituents on one pole of the fullerene and polyhydroxylation moieties, mostly ether and hydroxy groups, on the rest of the fullerene core. As substituents a broad variety of primary amines can be used to obtain Janus-type amphiphilic fullerenols in good to excellent yield. These fullerenol amphiphiles can serve as suitable precursors for further reactions resulting in new applications for fullerenols.
Keywords
- Amphiphile, C Cl, Fullerene, Fullerenol, One-pot
ASJC Scopus subject areas
- Chemistry(all)
- Organic Chemistry
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In: Beilstein Journal of Organic Chemistry, Vol. 15, 2019, p. 901-905.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Easy, efficient and versatile one-pot synthesis of Janus-type-substituted fullerenols
AU - Kunkel, Marius
AU - Polarz, Sebastian
N1 - Funding Information: The current research was funded by an ERC consolidator grant (I-SURF; project 614606).
PY - 2019
Y1 - 2019
N2 - An efficient one-pot synthesis for Janus-type fullerenol derivatives and how to characterize them is reported. This synthesis provides access to asymmetrically substituted fullerenol with five substituents on one pole of the fullerene and polyhydroxylation moieties, mostly ether and hydroxy groups, on the rest of the fullerene core. As substituents a broad variety of primary amines can be used to obtain Janus-type amphiphilic fullerenols in good to excellent yield. These fullerenol amphiphiles can serve as suitable precursors for further reactions resulting in new applications for fullerenols.
AB - An efficient one-pot synthesis for Janus-type fullerenol derivatives and how to characterize them is reported. This synthesis provides access to asymmetrically substituted fullerenol with five substituents on one pole of the fullerene and polyhydroxylation moieties, mostly ether and hydroxy groups, on the rest of the fullerene core. As substituents a broad variety of primary amines can be used to obtain Janus-type amphiphilic fullerenols in good to excellent yield. These fullerenol amphiphiles can serve as suitable precursors for further reactions resulting in new applications for fullerenols.
KW - Amphiphile
KW - C Cl
KW - Fullerene
KW - Fullerenol
KW - One-pot
UR - http://www.scopus.com/inward/record.url?scp=85066480705&partnerID=8YFLogxK
U2 - 10.3762/bjoc.15.87
DO - 10.3762/bjoc.15.87
M3 - Article
VL - 15
SP - 901
EP - 905
JO - Beilstein Journal of Organic Chemistry
JF - Beilstein Journal of Organic Chemistry
SN - 1860-5397
ER -