Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids

Research output: Chapter in book/report/conference proceedingConference contributionResearchpeer review

Authors

  • F. Jirasit
  • C. H. Rüscher
  • L. Lohaus
  • P. Chindaprasirt

External Research Organisations

  • Rajamangala University of Technology Lanna (RMUTL)
  • Khon Kaen University
View graph of relations

Details

Original languageEnglish
Title of host publicationDevelopments in Strategic Ceramic Materials II
Subtitle of host publicationCeramic Engineering and Science
EditorsWaltraud M. Kriven, Yanchun Zhou, Jingyang Wang, Dongming Zhu, Gustavo Costa
PublisherAmerican Ceramic Society
Pages3-12
Number of pages10
Volume37
Edition7
ISBN (electronic)9781119321811
ISBN (print)9781119040439
Publication statusPublished - 30 Jan 2017
EventDevelopments in Strategic Ceramic Materials II - 40th International Conference on Advanced Ceramics and Composites, ICACC 2016 - Daytona Beach, United States
Duration: 24 Jan 201629 Jan 2016

Publication series

NameCeramic Engineering and Science Proceedings
Number7
Volume37
ISSN (Print)0196-6219

Abstract

The durability performance of Alkali-Activated Cements (AAC) i.e., metakaolin (AAMK), slag (AAH), fly ash (AAB), and their hybrids (AAMK/H, AAMK/B) were carried out by a carbonation test and degradation test in sulfuric acid pH 0.5. The effect of carbonation was followed by IR absorption spectroscopy, KBr method. Ordinary Portland Cement (OPC), modified-OPC, and AAC were monitored for 11 weeks. Series of AAMK, AAH, AAB, and their hybrids were prepared using 2 types of alkaline activator (K0.5 and K0.64) and their deterioration were monitored for 9 weeks. Any accelerated carbonation could be ruled out in the case of AAMK, while it occurred the more the higher the CaO content of the raw material. In those materials carbonation occurred with the possible formation of vaterite which split in the IR bands at about 1420 and 1490 cm-1 before exposure. Further reaction was detected by increasing the intensity of vaterite phase after being exposed to CO2 of 3 vol%. For the sulfuric acid, the AAC revealed much better compared to OPC. A comparison between 2 types of alkaline activator revealed that higher alkaline content yielded more deterioration. As compared between sources of starting materials, AAB tended to resist acid attack better than did AAMK. However, the AAB showed significant formation of cracks. The results are also discussed with respect to their long term mechanical properties followed over 5 years.

ASJC Scopus subject areas

Cite this

Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids. / Jirasit, F.; Rüscher, C. H.; Lohaus, L. et al.
Developments in Strategic Ceramic Materials II: Ceramic Engineering and Science. ed. / Waltraud M. Kriven; Yanchun Zhou; Jingyang Wang; Dongming Zhu; Gustavo Costa. Vol. 37 7. ed. American Ceramic Society, 2017. p. 3-12 (Ceramic Engineering and Science Proceedings; Vol. 37, No. 7).

Research output: Chapter in book/report/conference proceedingConference contributionResearchpeer review

Jirasit, F, Rüscher, CH, Lohaus, L & Chindaprasirt, P 2017, Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids. in WM Kriven, Y Zhou, J Wang, D Zhu & G Costa (eds), Developments in Strategic Ceramic Materials II: Ceramic Engineering and Science. 7 edn, vol. 37, Ceramic Engineering and Science Proceedings, no. 7, vol. 37, American Ceramic Society, pp. 3-12, Developments in Strategic Ceramic Materials II - 40th International Conference on Advanced Ceramics and Composites, ICACC 2016, Daytona Beach, United States, 24 Jan 2016. https://doi.org/10.1002/9781119321811.ch1
Jirasit, F., Rüscher, C. H., Lohaus, L., & Chindaprasirt, P. (2017). Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids. In W. M. Kriven, Y. Zhou, J. Wang, D. Zhu, & G. Costa (Eds.), Developments in Strategic Ceramic Materials II: Ceramic Engineering and Science (7 ed., Vol. 37, pp. 3-12). (Ceramic Engineering and Science Proceedings; Vol. 37, No. 7). American Ceramic Society. https://doi.org/10.1002/9781119321811.ch1
Jirasit F, Rüscher CH, Lohaus L, Chindaprasirt P. Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids. In Kriven WM, Zhou Y, Wang J, Zhu D, Costa G, editors, Developments in Strategic Ceramic Materials II: Ceramic Engineering and Science. 7 ed. Vol. 37. American Ceramic Society. 2017. p. 3-12. (Ceramic Engineering and Science Proceedings; 7). doi: 10.1002/9781119321811.ch1
Jirasit, F. ; Rüscher, C. H. ; Lohaus, L. et al. / Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids. Developments in Strategic Ceramic Materials II: Ceramic Engineering and Science. editor / Waltraud M. Kriven ; Yanchun Zhou ; Jingyang Wang ; Dongming Zhu ; Gustavo Costa. Vol. 37 7. ed. American Ceramic Society, 2017. pp. 3-12 (Ceramic Engineering and Science Proceedings; 7).
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title = "Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids",
abstract = "The durability performance of Alkali-Activated Cements (AAC) i.e., metakaolin (AAMK), slag (AAH), fly ash (AAB), and their hybrids (AAMK/H, AAMK/B) were carried out by a carbonation test and degradation test in sulfuric acid pH 0.5. The effect of carbonation was followed by IR absorption spectroscopy, KBr method. Ordinary Portland Cement (OPC), modified-OPC, and AAC were monitored for 11 weeks. Series of AAMK, AAH, AAB, and their hybrids were prepared using 2 types of alkaline activator (K0.5 and K0.64) and their deterioration were monitored for 9 weeks. Any accelerated carbonation could be ruled out in the case of AAMK, while it occurred the more the higher the CaO content of the raw material. In those materials carbonation occurred with the possible formation of vaterite which split in the IR bands at about 1420 and 1490 cm-1 before exposure. Further reaction was detected by increasing the intensity of vaterite phase after being exposed to CO2 of 3 vol%. For the sulfuric acid, the AAC revealed much better compared to OPC. A comparison between 2 types of alkaline activator revealed that higher alkaline content yielded more deterioration. As compared between sources of starting materials, AAB tended to resist acid attack better than did AAMK. However, the AAB showed significant formation of cracks. The results are also discussed with respect to their long term mechanical properties followed over 5 years.",
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note = "Funding information: FJ is deeply indebted to Prof. Joseph Davidovits for his valuable discussions at the beginning of this research. FJ also thanks to Rajamangala University of Technology Lanna (RMUTL), Thailand, for supporting her stay abroad at Department for Building Materials, and Department of Mineralogy, both at University of Hannover, Germany. Special thanks to German Academic Exchange Service (DAAD) for funding the scholarship {\textquoteleft}Research Stays for University Academics and Scientists, 2015{\textquoteright} and also the travel grant by Leibniz Universit{\"a}t Hannover for my research visit to the Research Centre for Solid State Chemistry and New Materials (ZFM) at Leibniz Universit{\"a}t Hannover in June and July 2015. The University of Hannover is thanked for ACKNOWLEDGEMENTS FJ is deeply indebted to Prof. Joseph Davidovits for his valuable discussions at the beginning of this research. FJ also thanks to Rajamangala University of Technology Lanna (RMUTL), Thailand, for supporting her stay abroad at Department for Building Materials, and Department of Mineralogy, both at University of Hannover, Germany. Special thanks to German Academic Exchange Service (DAAD) for funding the scholarship {\textquoteleft}Research Stays for University Academics and Scientists, 2015{\textquoteright} and also the travel grant by Leibniz Universit{\"a}t Hannover for my research visit to the Research Centre for Solid State Chemistry and New Materials (ZFM) at Leibniz Universit{\"a}t Hannover in June and July 2015. The University of Hannover is thanked for; Developments in Strategic Ceramic Materials II - 40th International Conference on Advanced Ceramics and Composites, ICACC 2016 ; Conference date: 24-01-2016 Through 29-01-2016",
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Download

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T1 - Durability Performance of Alkali‐Activated Metakaolin, Slag, Fly Ash, and Hybrids

AU - Jirasit, F.

AU - Rüscher, C. H.

AU - Lohaus, L.

AU - Chindaprasirt, P.

N1 - Funding information: FJ is deeply indebted to Prof. Joseph Davidovits for his valuable discussions at the beginning of this research. FJ also thanks to Rajamangala University of Technology Lanna (RMUTL), Thailand, for supporting her stay abroad at Department for Building Materials, and Department of Mineralogy, both at University of Hannover, Germany. Special thanks to German Academic Exchange Service (DAAD) for funding the scholarship ‘Research Stays for University Academics and Scientists, 2015’ and also the travel grant by Leibniz Universität Hannover for my research visit to the Research Centre for Solid State Chemistry and New Materials (ZFM) at Leibniz Universität Hannover in June and July 2015. The University of Hannover is thanked for ACKNOWLEDGEMENTS FJ is deeply indebted to Prof. Joseph Davidovits for his valuable discussions at the beginning of this research. FJ also thanks to Rajamangala University of Technology Lanna (RMUTL), Thailand, for supporting her stay abroad at Department for Building Materials, and Department of Mineralogy, both at University of Hannover, Germany. Special thanks to German Academic Exchange Service (DAAD) for funding the scholarship ‘Research Stays for University Academics and Scientists, 2015’ and also the travel grant by Leibniz Universität Hannover for my research visit to the Research Centre for Solid State Chemistry and New Materials (ZFM) at Leibniz Universität Hannover in June and July 2015. The University of Hannover is thanked for

PY - 2017/1/30

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N2 - The durability performance of Alkali-Activated Cements (AAC) i.e., metakaolin (AAMK), slag (AAH), fly ash (AAB), and their hybrids (AAMK/H, AAMK/B) were carried out by a carbonation test and degradation test in sulfuric acid pH 0.5. The effect of carbonation was followed by IR absorption spectroscopy, KBr method. Ordinary Portland Cement (OPC), modified-OPC, and AAC were monitored for 11 weeks. Series of AAMK, AAH, AAB, and their hybrids were prepared using 2 types of alkaline activator (K0.5 and K0.64) and their deterioration were monitored for 9 weeks. Any accelerated carbonation could be ruled out in the case of AAMK, while it occurred the more the higher the CaO content of the raw material. In those materials carbonation occurred with the possible formation of vaterite which split in the IR bands at about 1420 and 1490 cm-1 before exposure. Further reaction was detected by increasing the intensity of vaterite phase after being exposed to CO2 of 3 vol%. For the sulfuric acid, the AAC revealed much better compared to OPC. A comparison between 2 types of alkaline activator revealed that higher alkaline content yielded more deterioration. As compared between sources of starting materials, AAB tended to resist acid attack better than did AAMK. However, the AAB showed significant formation of cracks. The results are also discussed with respect to their long term mechanical properties followed over 5 years.

AB - The durability performance of Alkali-Activated Cements (AAC) i.e., metakaolin (AAMK), slag (AAH), fly ash (AAB), and their hybrids (AAMK/H, AAMK/B) were carried out by a carbonation test and degradation test in sulfuric acid pH 0.5. The effect of carbonation was followed by IR absorption spectroscopy, KBr method. Ordinary Portland Cement (OPC), modified-OPC, and AAC were monitored for 11 weeks. Series of AAMK, AAH, AAB, and their hybrids were prepared using 2 types of alkaline activator (K0.5 and K0.64) and their deterioration were monitored for 9 weeks. Any accelerated carbonation could be ruled out in the case of AAMK, while it occurred the more the higher the CaO content of the raw material. In those materials carbonation occurred with the possible formation of vaterite which split in the IR bands at about 1420 and 1490 cm-1 before exposure. Further reaction was detected by increasing the intensity of vaterite phase after being exposed to CO2 of 3 vol%. For the sulfuric acid, the AAC revealed much better compared to OPC. A comparison between 2 types of alkaline activator revealed that higher alkaline content yielded more deterioration. As compared between sources of starting materials, AAB tended to resist acid attack better than did AAMK. However, the AAB showed significant formation of cracks. The results are also discussed with respect to their long term mechanical properties followed over 5 years.

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