Details
| Original language | English |
|---|---|
| Pages (from-to) | 3367-3370 |
| Number of pages | 4 |
| Journal | Chemical communications |
| Volume | 55 |
| Issue number | 23 |
| Early online date | 26 Feb 2019 |
| Publication status | Published - 21 Mar 2019 |
Abstract
The postsynthetic potential of the two-dimensional metal-organic framework Zr-bzpdc-MOF which is based on the photoreactive molecule benzophenone-4,4′-dicarboxylic acid (H2bzpdc) is used here to selectively functionalize the MOF surface. We report the direct radical-induced oxidative grafting-from polymerization of the precursor EDOT on Zr-bzpdc-MOF, leading to an electrically conductive composite material and opening the road to a variety of applications.
ASJC Scopus subject areas
- Chemical Engineering(all)
- Catalysis
- Materials Science(all)
- Electronic, Optical and Magnetic Materials
- Materials Science(all)
- Ceramics and Composites
- Chemistry(all)
- General Chemistry
- Materials Science(all)
- Surfaces, Coatings and Films
- Materials Science(all)
- Metals and Alloys
- Materials Science(all)
- Materials Chemistry
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In: Chemical communications, Vol. 55, No. 23, 21.03.2019, p. 3367-3370.
Research output: Contribution to journal › Article › Research › peer review
}
TY - JOUR
T1 - Direct grafting-from of PEDOT from a photoreactive Zr-based MOF - a novel route to electrically conductive composite materials
AU - Mohmeyer, Alexander
AU - Schaate, Andreas
AU - Hoppe, Bastian
AU - Schulze, Hendrik A.
AU - Heinemeyer, Thea
AU - Behrens, Peter
N1 - Funding information: This work was partially funded by the DFG EXC 1077/1 ‘‘Hearing4all’’. We thank Katharina Nolte for thermogravimetric analysis and Claudia Schulze for elemental analysis. Also we thank the Institute for Organic Chemistry (Leibniz University Hannover) for performing NMR spectroscopy measurements.
PY - 2019/3/21
Y1 - 2019/3/21
N2 - The postsynthetic potential of the two-dimensional metal-organic framework Zr-bzpdc-MOF which is based on the photoreactive molecule benzophenone-4,4′-dicarboxylic acid (H2bzpdc) is used here to selectively functionalize the MOF surface. We report the direct radical-induced oxidative grafting-from polymerization of the precursor EDOT on Zr-bzpdc-MOF, leading to an electrically conductive composite material and opening the road to a variety of applications.
AB - The postsynthetic potential of the two-dimensional metal-organic framework Zr-bzpdc-MOF which is based on the photoreactive molecule benzophenone-4,4′-dicarboxylic acid (H2bzpdc) is used here to selectively functionalize the MOF surface. We report the direct radical-induced oxidative grafting-from polymerization of the precursor EDOT on Zr-bzpdc-MOF, leading to an electrically conductive composite material and opening the road to a variety of applications.
UR - http://www.scopus.com/inward/record.url?scp=85062872620&partnerID=8YFLogxK
U2 - 10.1039/c8cc10298h
DO - 10.1039/c8cc10298h
M3 - Article
C2 - 30816376
AN - SCOPUS:85062872620
VL - 55
SP - 3367
EP - 3370
JO - Chemical communications
JF - Chemical communications
SN - 1359-7345
IS - 23
ER -